24171-89-9

Usage

Uses

Used in Pharmaceutical Industry:
TRIS(2-THIENYL)PHOSPHINE is used as an intermediate for the synthesis of various pharmaceutical compounds. Its unique chemical structure allows it to be a key component in the development of new drugs, particularly those targeting specific biological pathways or receptors.
Used in Organic Synthesis:
In the field of organic synthesis, TRIS(2-THIENYL)PHOSPHINE is employed as a versatile reagent and catalyst. Its ability to form stable complexes with various metal ions makes it a valuable tool in the synthesis of complex organic molecules, including those with potential applications in materials science, agrochemicals, and other industries.
Used in Catalyst Formulation:
Due to its ability to form stable complexes with metal ions, TRIS(2-THIENYL)PHOSPHINE is used as a component in the formulation of catalysts for various chemical reactions. These catalysts can be employed in a wide range of applications, from the production of fine chemicals to the synthesis of polymers and other materials.
Used in Research and Development:
TRIS(2-THIENYL)PHOSPHINE is also utilized in research and development settings, where its unique properties can be explored for the development of new chemical processes, materials, and pharmaceutical compounds. Its potential applications in various industries make it an important compound for scientists and researchers to study and understand.

InChI:InChI=1/C12H9PS3/c1-4-10(14-7-1)13(11-5-2-8-15-11)12-6-3-9-16-12/h1-9H

Upstream product

• 1003-09-4 2-bromothiophene 
• 188290-36-0 thiophene 

Downstream Products

• 1021-21-2 tris(thiophen-2-yl)phosphine oxide 
• 24111-71-5 Tri-[2]thienyl-phosphinsulfid 
• 95517-74-1 <3-bromo-6-(4-diethylaminophenylazo)phenyl>tri-2-thienylphosphonium bromide 
• 26910-74-7 tri(2-thienyl)phosphine selenide 
• 1095751-07-7 Ru3(CO)9(tri(2-thienyl)phosphine)(μ-bis(diphenylphosphino)methane) 
• 1191451-54-3 Ru3(CO)9(tri(2-thienyl)phosphine)(μ-1,3-diphenyl-2,3-dihydro-1H-1,3-benzodiphosphine) 
• 1416778-31-8 methyl 2-(4-nitrophenyl)-5-oxo-4-(tri-2-thienyl-λ⁵-phosphanylidene)-4,5-dihydrofuran-3-carboxylate 
• 91311-62-5 [Os3(CO)10(μ-bis(diphenylphosphino)methane)] 
• 1551570-34-3 [Os₃(CO)₉(tri(2-thienyl)phosphine)(μ-dppm)] 
• 1551570-40-1 [Os₃(CO)₈(tri(2-thienyl)phosphine)₂(μ-dppm)] 

Relevant academic research and scientific papers

A Lewis Base Nucleofugality Parameter, NFB, and Its Application in an Analysis of MIDA-Boronate Hydrolysis Kinetics

The kinetics of quinuclidine displacement of BH3 from a wide range of Lewis base borane adducts have been measured. Parameterization of these rates has enabled the development of a nucleofugality scale (NFB), shown to quantify and predict the leaving group ability of a range of other Lewis bases. Additivity observed across a number of series R′3-nRnX (X = P, N; R′ = aryl, alkyl) has allowed the formulation of related substituent parameters (nfPB, nfAB), providing a means of calculating NFB values for a range of Lewis bases that extends far beyond those experimentally derived. The utility of the nucleofugality parameter is explored by the correlation of the substituent parameter nfPB with the hydrolyses rates of a series of alkyl and aryl MIDA boronates under neutral conditions. This has allowed the identification of MIDA boronates with heteroatoms proximal to the reacting center, showing unusual kinetic lability or stability to hydrolysis.

Ir(III)-catalyzed direct C-H functionalization of arylphosphine oxides: A strategy for MOP-type ligands synthesis

Diazo compounds as coupling partners are efficiently applied to Ir(III)-catalyzed direct C-H functionalization of arylphos-phine oxides. Involving C-H activation, carbene insertion, and tautomerism, this reaction proceeds under mild conditions, thus proving an approach to the synthesis of MOP-type ligand precursor in a single step. The utility of this transformation has been further demonstrated in ligand synthesis as well as in the construction of phosphole framework.

PHOSPHORYLATION OF FURAN, 2-METHYLFURAN, AND THIOPHENE WITH PHOSPHORUS TRIBROMIDE

In the presence of pyridine phophorus tribromide is a convenient phosphorylating agent for compounds of furan and thiophene series.Preparative methods for the synthesis of phophorylated furan, 2-methylfuran, and thiophene derivatives were developed.

SYNTHESIS OF SOME LIGANDS OF THE TRITHIENYLPHOSPHINE SERIES. CRYSTAL AND MOLECULAR STRUCTURES OF trans-DICHLOROBISPALLADIUM(II)

The preparation of some ligands of the trithienylphosphine series is described; Pd(II) complexes were obtained from them.The crystal and molecular structures of trans-dichlorobispalladium(II) were studied.