241824-87-3

Basic information

• Product Name: Benzyl-[1-{(4S,5S)-5-[(Z)-(R)-1-(tert-butyl-dimethyl-silanyloxy)-tetradec-2-enyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-meth-(E)-ylidene]-amine
• Synonyms: Benzyl-[1-{(4S,5S)-5-[(Z)-(R)-1-(tert-butyl-dimethyl-silanyloxy)-tetradec-2-enyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-meth-(E)-ylidene]-amine
• CAS NO: 241824-87-3
• Molecular Weight: 543.906
• Mol File: 241824-87-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzyl-[1-{(4S,5S)-5-[(Z)-(R)-1-(tert-butyl-dimethyl-silanyloxy)-tetradec-2-enyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-meth-(E)-ylidene]-amine(CAS DataBase Reference)
• NIST Chemistry Reference: Benzyl-[1-{(4S,5S)-5-[(Z)-(R)-1-(tert-butyl-dimethyl-silanyloxy)-tetradec-2-enyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-meth-(E)-ylidene]-amine(241824-87-3)
• EPA Substance Registry System: Benzyl-[1-{(4S,5S)-5-[(Z)-(R)-1-(tert-butyl-dimethyl-silanyloxy)-tetradec-2-enyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-meth-(E)-ylidene]-amine(241824-87-3)

Safety Data

• Hazardous Substances Data: 241824-87-3(Hazardous Substances Data)

Upstream product

• 100-46-9 benzylamine 
• 241824-86-2 (4R,5S)-5-[(Z)-(R)-1-(tert-Butyl-dimethyl-silanyloxy)-tetradec-2-enyl]-2,2-dimethyl-[1,3]dioxolane-4-carbaldehyde 
• 241824-83-9 [(R)-1-((4S,5S)-5-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-tetradec-2-ynyloxy]-tert-butyl-dimethyl-silane 
• 241824-84-0 [(Z)-(R)-1-((4S,5S)-5-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-tetradec-2-enyloxy]-tert-butyl-dimethyl-silane 
• 241824-85-1 {(4S,5S)-5-[(Z)-(R)-1-(tert-Butyl-dimethyl-silanyloxy)-tetradec-2-enyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-methanol 
• 241824-81-7 (R)-1-((4R,5S)-5-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-tetradec-2-yn-1-ol 
• 136136-23-7 meso-1,4-O-butyryl-2,3-isopropylidene-erythritol 
• 81801-08-3 4-O-benzyl-2,3-O-isopropylidene-aldehydo-D-erythrose 
• 502481-96-1 (2S,3R)-4-benzyloxy-2,3-(propane-2,2-dioxy)-1-butanol 
• 56543-05-6 (4R,5S)-diethyl 2,2-dimethyl-1,3-dioxolane-4,5-dicarboxylate 
• 55904-12-6 ((4R,5S)-5-Hydroxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-methanol 

Downstream Products

• 241824-97-5 Benzyl-((S)-2-benzyloxy-1-{(4S,5S)-5-[(Z)-(R)-1-(tert-butyl-dimethyl-silanyloxy)-tetradec-2-enyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-ethyl)-amine 

Relevant articles and documents

Highly stereocontrolled access to a tetrahydroxy long chain base using anti-selective additions

Complete diastereostereoselection was attained for the addition of acetylide and benzyloxymethyl anions to a chiral aldehyde and an imine derived from meso-tartaric acid, leading to a facile synthesis of (2S,3S,4R,5R,6Z)-2-amino-1,3,4,5-tetrahydroxyoctadecene as its pentaacetyl derivative in enantiomerically pure form.