24197-41-9

Basic information

• Product Name: 4-amino-3-tert-butylphenol
• Synonyms: 4-amino-3-tert-butylphenol
• CAS NO: 24197-41-9
• Molecular Formula: C₁₀H₁₅NO
• Molecular Weight: 165.2322
• Mol File: 24197-41-9.mol
• Article Data: 4

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 4-amino-3-tert-butylphenol(CAS DataBase Reference)
• NIST Chemistry Reference: 4-amino-3-tert-butylphenol(24197-41-9)
• EPA Substance Registry System: 4-amino-3-tert-butylphenol(24197-41-9)

Safety Data

• Hazardous Substances Data: 24197-41-9(Hazardous Substances Data)

Upstream product

• 585-34-2 3-tert-butylphenyol 
• 720712-00-5 2-tert-butyl-4-methoxy-phenylamine 
• 121-57-3 4-aminobenzene sulfonic acid 

Downstream Products

• 1190867-70-9 N-(4-acetyloxy-2-tert-butyl-phenyl)-acetamide 
• 1373751-83-7 1-azido-2-tert-butyl-4-methoxybenzene 
• 87234-77-3 3,3-dimethyl-5-methoxy-indoline 
• 1352342-92-7 ethyl 6-(benzyloxy)-8-tert-butyl-4-hydroxyquinoline-2-carboxylate 
• 1443926-67-7 (1S,3R)-3-(5-(8-tert-butyl-4-methyl-6-(2,2,2-trifluoroethylamino)quinolin-2-yl)-1,3,4-oxadiazol-2-ylamino)cyclohexanol 
• 1352342-94-9 ethyl 6-(benzyloxy)-8-tert-butyl-4-methylquinoline-2-carboxylate 
• 1352342-93-8 ethyl 6-(benzyloxy)-8-(tert-butyl)-4-(((trifluoromethyl)sulfonyl)oxy)quinoline-2-carboxylate 
• 1443755-62-1 8-tert-butyl-4-methyl-6-(2,2,2-trifluoroethylamino)quinoline-2-carbohydrazide 
• 1352342-91-6 4-(benzyloxy)-2-(tert-butyl)aniline 

Relevant articles and documents

Catalytic C(sp3)?H Arylation of Free Primary Amines with an exo Directing Group Generated In Situ

Herein, we report the palladium-catalyzed direct arylation of unactivated aliphatic C?H bonds in free primary amines. This method takes advantage of an exo-imine-type directing group (DG) that can be generated and removed in situ. A range of unprotected aliphatic amines are suitable substrates, undergoing site-selective arylation at the γ-position. Methyl as well as cyclic and acyclic methylene groups can be activated. Furthermore, when aniline-derived substrates were used, preliminary success with δ-C?H arylation was achieved. The feasibility of using the DG component in a catalytic fashion was also demonstrated.

Palladium-catalyzed amidation of unactivated c(sp3)-h bonds: From anilines to indolines

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