24208-10-4Relevant academic research and scientific papers
A NEW POWERFUL AND SELECTIVE REDUCING AGENT SODIUM BOROHYDRIDE-PALLADIUM CHLORIDE SYSTEM
Satoh, Toshio,Mitsuo, Naoki,Nishiki, Mayumi,Nanba, Kenryo,Suzuki, Shuichi
, p. 1029 - 1030 (1981)
A new reducing agent, sodium borohydride-palladium chloride system reduces aryl ketones, aryl chlorides, and benzylic alcohols to corresponding hydrocarbons.It also reduces hindered steroidal ketones to alcohols in good yields.
STEROIDS .LIII. TRANSFORMATION OF 3β-ACETOXY-5α-ANDROSTAN-17-ONE INTO 17α- AND 17β-AMINO DERIVATIVES OF 5α-ANDROSTAN-3β-OL
Nadaraia, N. Sh.,Sladkov, V. I.,Kuleshova, L. N.,Suvorov, N. N.
, p. 481 - 485 (2007/10/02)
The epimeric 17α- and 17β-amino-5α-androstan-3β-ols were synthesized from 3β-acetoxy-5α-androstan-17-one.The configurations at the C17 atom were demonstrated by the 1H NMR method.
