242129-65-3Relevant academic research and scientific papers
Synthesis of 4-octuloses, V. - 4-Octulose derivatives as key intermediates in a new and short synthesis of polyhydroxyindolizidines
Izquierdo, Isidoro,Plaza, Maria T.,Robles, Rafael,Rodriguez, Concepcion,Ramirez, Antonio,Mota, Antonio J.
, p. 1269 - 1274 (1999)
Reaction of 3 with (cyanomethylene)triphenylphosphorane in refluxing dichloromethane or methanol gave mixtures of 4a and 4b in ratios of about 3:1 and 1:3, respectively. The same reaction performed with the furanoid isomer 5 afforded 6a and 6b in (E)/(Z)
