24253-06-3Relevant academic research and scientific papers
Reaction of carbonyl compounds with xenon difluoride in the presence of silicon tetrafluoride
Tamura, Masanori,Matsukawa, Yasuhisa,Quan, Heng-Dao,Mizukado, Junji,Sekiya, Akira
, p. 705 - 709 (2004)
Reaction of various carbonyl compounds with xenon difluoride in the presence of silicon tetrafluoride was investigated. Aromatic aldehyde, ketones, and α-ketoester react with xenon difluoride to give α,α-difluoroalkyl phenyl ethers. However, acid fluoride, ester, acid cyanide, α-ketocarboxylic acid, or thioester do not afford the corresponding products. In the case of cinnamaldehyde, fluorination was accompanied by intramolecular cyclization to afford fluorinated epoxide.
