2432-79-3Relevant academic research and scientific papers
Synthesis of S-Alkyl Alkanethioates via 1-Iodoalk-1-enyldialkylboranes
Hoshi, Masayuki,Masuda, Yuzuru,Arase, Akira
, p. 714 - 715 (1985)
S-Alkyl alkanethioates were formed in high yields by successive reactions of 1-iodoalk-1-enyl-bis(1,2-dimethylpropyl)boranes with alkylthiomagnesium bromides and alkaline hydrogen peroxide.
The hydroboration of 1-alkylthio-1-alkynes, and its application to the syntheses of s-alkyl alkanethioates and (Z)-1-alkylthio-1-alkenes
Hoshi,Masuda,Arase
, p. 447 - 452 (2007/10/02)
Hydroboration of 1-alkylthio-1-alkynes with dicyclohexylborane or bis(1,2-dimethylpropyl)borane proceeded smoothly, adding most of the dialkylboryl group to the α-position of the triple bond. The resulting alkenylboranes afforded either S-alkyl alkanethio
