24344-65-8

Basic information

• Product Name: N-BUTYLTRIETHYLAMMONIUM CHLORIDE
• Synonyms: N-BUTYLTRIETHYLAMMONIUM CHLORIDE;N-Butyl-N,N,N-triethylammonium chloride
• CAS NO: 24344-65-8
• Molecular Formula: C₁₀H₂₄N*Cl
• Molecular Weight: 193.76
• Mol File: 24344-65-8.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: N-BUTYLTRIETHYLAMMONIUM CHLORIDE(CAS DataBase Reference)
• NIST Chemistry Reference: N-BUTYLTRIETHYLAMMONIUM CHLORIDE(24344-65-8)
• EPA Substance Registry System: N-BUTYLTRIETHYLAMMONIUM CHLORIDE(24344-65-8)

Safety Data

• Hazardous Substances Data: 24344-65-8(Hazardous Substances Data)

Upstream product

• 109-69-3 n-Butyl chloride 
• 121-44-8 triethylamine 

Downstream Products

• 122143-18-4 1-(2-Chlorophenyl)-cyclopropane-carbonitrile 
• 958877-36-6 [Pd(2-tert-butylthiomethylpyridine)(1-(2,6-dimethylphenylimino)ethyl)Cl] 
• 958877-41-3 [Pd(8-diphenylphosphanylquinoline)(1-(2,6-dimethylphenylimino)ethyl)Cl] 

Relevant articles and documents

The study of industrializable ionic liquid catalysts for long-chain alkenes Friedel–Crafts alkylation

Catalysts based on different halo-alkanes structures with durable catalytic performance were synthesized and applied to the Friedel–Crafts alkylation of long-chain alkenes (mixed C16–24 olefins) with toluene. Surprisingly, compared with the usual industrial catalysts (~10 runs), the cyclic times of the ionic liquid (IL) catalysts reached up to 24 runs, which greatly promotes the industrialization process. Then, Lewis acids of catalysts with different precursor/AlCl3 molar ratios were investigated and a close relation was discovered between the Lewis acid and catalytic activity. In addition, a comparison of the different halo-alkanes structures about those catalysts was made. The results showed that the [C6Et3N]Cl–AlCl3 had the strongest Lewis acid, corresponding to the highest catalytic performance. Also, the structures of precursors and the specific gravity and active site species of catalysts were investigated by Fourier transform infrared and Magic Angle Spinning Nuclear Magnetic Resonance (MAS NMR). Meanwhile, the various parameters (catalyst dosage, toluene/olefin molar ratio, reaction temperature and reaction time) of long-chain alkenes alkylation with toluene were studied. Finally, under the optimized reaction conditions, the conversion and selectivity of long-chain alkenes alkylation reached 99.92 and 32.99percent, respectively.

Ionic liquid droplet as e-microreactor

A powerful approach combining a droplet-based, open digital microfluidic lab-on-a-chip using task-specific ionic liquids as soluble supports to perform solution-phase synthesis is reported as a new tool for chemical applications. The negligible volatility of ionic liquids enables their use as stable droplet reactors on a chip surface under air. The concept was validated with different ionic liquids and with a multicomponent reaction. Indeed, we showed that different ionic liquids can be moved by electrowetting on dielectric (EWOD), and their displacement was compared with aqueous solutions. Furthermore, we showed that mixing ionic liquids droplets, each containing a different reagent, in "open" systems is an efficient way of carrying supported organic synthesis. This was applied to Grieco's tetrahydroquinolines synthesis with different reagents. Analysis of the final product was performed off-line and on-line, and the results were compared with those obtained in a conventional reaction flask. This technology opens the way to easy synthesis of minute amounts of compounds ad libitum without the use of complex, expensive, and bulky robots and allows complete automation of the process for embedded chemistry in a portable device. It offers several advantages, including simplicity of use, flexibility, and scalability, and appears to be complementary to conventional microfluidic lab-on-a-chip devices usually based on continuous-flow in microchannels.