243671-25-2

Upstream product

• 108-94-1 cyclohexanone 
• 70-55-3 toluene-4-sulfonamide 
• 762-72-1 allyl-trimethyl-silane 
• 66838-79-7 1-allyl-1-aminocyclohexane 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 1285256-88-3 N-(1-allylcyclohexyl)-4-methyl-N-(3-methyl-2-methylenebut-3-enyl)benzenesulfonamide 
• 1285257-01-3 (3R,4R)-3-methyl-3-(prop-1-en-2-yl)-1-tosyl-4-vinyl-1-azaspiro[4.5]decane 

Relevant academic research and scientific papers

Imine allylation by allylic trimethylsilanes via in situ formation of N-tosyliminium species from carbonyl compounds and toluene-p-sulfonamide with SnCl2 and N-chlorosuccinimide: Regioselection and diastereoselection

N-Tosyliminium species, prepared in situ from carbonyl compounds and TsNH2 with SnCl2 and N-chlorosuccinimide, undergo nucleophilic addition of allylic silanes (imine allylation) to produce the corresponding homoallylic amines; the i

Palladium-catalyzed carbonylation of homoallylic amine derivatives in the presence of a copper co-catalyst

γ-Lactams were synthesized from N-tosylhomoallylamines by a carbonylation reaction catalyzed by palladium and copper salts under the normal pressure of CO and O2 at room temperature. Monocarbonylation proceeded by the use of [PdCl2(C