2437-98-1Relevant academic research and scientific papers
Ruthenium catalysed reduction of alkenes using sodium borohydride
Adair, Gareth R.A.,Kapoor, Kamal K.,Scolan, Alexandre L.B.,Williams, Jonathan M.J.
, p. 8943 - 8944 (2007/10/03)
The reduction of alkenes has been achieved using NaBH4 as the reducing agent using 0.5-1.0 mol % Ru(PPh3)4H2 in the presence of water.
EFFECT OF THE STRUCTURE OF THE AMINE ON THE RATE OF BASE-CATALYZED ACYLATION OF ALKYL AROMATIC AMINES BY BENZOYL CHLORIDE AND 2,4-DINITROPHENYL ACETATE
Oleinik, N. M.,Sadovskii, Yu. S.,Litvinenko, L. M.,Radchenko, N. D.,Korzhilova, L. I.
, p. 1144 - 1152 (2007/10/02)
The kinetics of the noncatalytic and base-catalyzed aminolysis of benzoyl chloride (with pyridine as catalyst) and 2,4-dinitrophenyl acetate (with pyridine, ε-caprolactam and pyridine N-oxide as catalysts) by alkyl aromatic amines PhNHR were studied in benzene at 25 deg C.The obtained rate constants are described satisfactorily by the modified Taft equation, which takes account of the steric and inductive effects of the structure of the amine.The results are discussed in terms of base and nucleophilic mechanisms of catalysis.
