243849-46-9Relevant academic research and scientific papers
Synthesis of the C29-C37 segment of spongistatin 1
Dunkel, Ralf,Treu, Jens,Martin,Hoffmann
, p. 1539 - 1549 (1999)
Starting from racemic 2α-methyl-8-oxabicyclo[3.2.1]oct-6-en-3-one the spongistatin E segment has been prepared in nine steps (2.3 steps per stereogenic center) with umpolung of anomeric reactivity at C37. This 3,5- syndiol sequence completes our methodolo
