243970-07-2Relevant academic research and scientific papers
The synthesis and conformation of oxygenated trianglimine macrocycles
Kuhnert, Nikolai,Lopez-Periago, Ana,Rossignolo, Giulia M.
, p. 524 - 537 (2005)
The synthesis of series of D2h and C2v symmetric oxygenated aromatic dicarboxaldehydes, using dilithiation methodology, is described along with their reactivity in the [3 + 3] cyclocondensation reaction with (1R,2R)-diaminocyclohexane to give oxygenated trianglimine macrocycles. Macrocycles derived from C2v symmetric dialdehydes give macrocycles with a stereogenic aromatic plane with complete diastereocontrol, as a mixture of retainers.
Preparation and nonlinear optics of monodisperse oligo(1,4-phenyleneethynylene)s
Meier, Herbert,Ickenroth, Dirk,Stalmach, Ulf,Koynov, Kaloian,Bahtiar, Ayi,Bubeck, Christoph
, p. 4431 - 4443 (2007/10/03)
Oligo(1,4-phenyleneethynylene)s 1a-e, with solubilizing propoxy side chains, were prepared by use of Hagihara-Sonogashira coupling reactions. The synthetic strategy was based on a building block system and on the use of trimethylsilyl and triisopropylsily
