244004-92-0

Upstream product

• 131956-11-1 [5-(4′-aminophenyl)-10,15,20-triphenylporphyrinato]zinc(II) 
• 133308-61-9 4'-methyl-2,2'-bipyridinyl-4-carbonyl chloride 
• 5970-45-6 zinc(II) acetate dihydrate 

Downstream Products

• 444159-82-4 Zn(5,10,15-triphenyl-20-(3-NHC(O)(3'-methylbipyridyl))phenylporphine) anion-radical 
• 244004-91-9 Zn(C₅₆H₃₇N₇O)ReBr(CO)3 

Relevant academic research and scientific papers

Zinc porphyrin-re(I) bipyridyl-fullerene triad: Synthesis, characterization, and kinetics of the stepwise electron-transfer processes initiated by visible excitation

A new triad system featuring one zinc porphyrin and one fullerene moieties attached to a central redox-active Re(I) connector was obtained in remarkable yield by cleverly exploiting a facile two-step synthesis. Detailed description and discussion on the characterization of this multicomponent system and of its parent free-base analogue are presented, along with a kinetic study of the stepwise electron-transfer processes occurring upon visible excitation.

Systematic synthesis and photochemistry of tetraaryl porphyrins mono-substituted with a transition metal carbonyl: characterisation of a zinc porhyrin-rhenium carbonyl complex

A systematic synthesis designed to connect a metalloporphyrin to a metal carbonyl moiety is demonstrated through a zinc tetraphenyl porphyrin substituted with Re(CO)3(4'-methyl-2,2'-bipyridyl)Br via an amide bond; the emission and excited state absorption spectra are dominated by porphyrin transitions.