244137-39-1Relevant academic research and scientific papers
Direct transformation of silyl enol ethers into functionalized allenes
Langer, Peter,Doering, Manfred,Seyferth, Dietmar,Goerls, Helmar
, p. 573 - 584 (2007/10/03)
The first elimination reactions of silyl enol ethers to lithiated allenes are reported. These reactions allow a direct transformation of readily available silyl enol ethers into functionalized allenes. The action of three to four equivalents of lithium di
Synthesis and domino reactions of 1,1-bis(hydroxymethyl)allenes
Langer, Peter
, p. 1217 - 1218 (2007/10/03)
The reaction of dilithiated 1,1-diphenylallene with aryl ketones provides a convenient access to novel 1,1-bis(hydroxymethyl)allenes, which undergo Friedel-Crafts-type domino reactions upon treatment with TsOH.
