244277-79-0

Basic information

• Product Name: toluene-4-sulfonic acid-(4-methoxy-2-methyl-anilide)
• Synonyms: toluene-4-sulfonic acid-(4-methoxy-2-methyl-anilide)
• CAS NO: 244277-79-0
• Molecular Weight: 291.371
• Mol File: 244277-79-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: toluene-4-sulfonic acid-(4-methoxy-2-methyl-anilide)(CAS DataBase Reference)
• NIST Chemistry Reference: toluene-4-sulfonic acid-(4-methoxy-2-methyl-anilide)(244277-79-0)
• EPA Substance Registry System: toluene-4-sulfonic acid-(4-methoxy-2-methyl-anilide)(244277-79-0)

Safety Data

• Hazardous Substances Data: 244277-79-0(Hazardous Substances Data)

Upstream product

• 98-59-9 p-toluenesulfonyl chloride 
• 102-50-1 2-methyl-4-methoxyaniline 

Relevant articles and documents

Highly chemo- and regioselective C-P cross-coupling reaction of quinone imine ketals with Ar2P(O)H to construct: Ortho -amino triarylphosphine derivatives

A highly chemo- and regioselective approach for the construction of ortho-amino triarylphosphine oxides has been achieved through a C-P cross-coupling reaction involving quinone imine ketals (QIKs) with Ar2P(O)H and catalyzed via a Lewis base. This alternative protocol provided a wide substrate scope with excellent yields (82-95%), and a variety of ortho-amino triarylphosphines were obtained with high yields (87-95%) via further reductive reaction. Furthermore, this reaction could be scaled-up and several synthetic transformations were accomplished for the construction of functionalized organophosphorus.