24437-56-7

Downstream Products

• 58058-80-3 1-((E)-1,2-Bis-methylsulfanyl-vinyl)-4-chloro-benzene 
• 58058-78-9 1-Chloro-4-((Z)-2-methanesulfonyl-1-methylsulfanyl-vinyl)-benzene 
• 58058-79-0 1-Chloro-4-((E)-2-methanesulfonyl-2-methylsulfanyl-vinyl)-benzene 
• 1519058-79-7 2-[(4-chlorophenyl)ethynyl]tetrahydrofuran 
• 58058-93-8 1-Chloro-4-((Z)-2-methanesulfonyl-2-methylsulfanyl-vinyl)-benzene 
• 58058-91-6 1-Chloro-4-((E)-2-methanesulfonyl-1-methylsulfanyl-vinyl)-benzene 

Relevant academic research and scientific papers

Photoinduced remote regioselective radical alkynylation of unactivated C-H bonds

A method for the remote regioselective alkynylation of unactivated C(sp3)-H bonds in diverse aliphatic amides by photogenerated amidyl radicals has been developed. The site-selectivity is dominated via a 1,5-hydrogen atom transfer (HAT) process of the amide. Mild reaction conditions and high regioselectivity are demonstrated in this methodology.

Decatungstate as Direct Hydrogen Atom Transfer Photocatalyst for SOMOphilic Alkynylation

A versatile approach for the alkynylation of a variety of aliphatic hydrogen donors, including alkanes, is reported. We used tetrabutylammonium decatungstate as photocatalyst to generate organoradicals from C-H/Si-H bonds via hydrogen atom transfer. The l