24499-04-5

Upstream product

• 75-07-0 acetaldehyde 
• 62-53-3 aniline 
• 134-81-6 benzil 
• 2627-86-3 (S)-1-phenyl-ethylamine 
• 5326-56-7 N-(α'-oxo-bibenzyl-α-yl)-acetanilide 

Relevant academic research and scientific papers

2-methyl-1,4,5-triphenyl-1H-imidazole

In 2-methyl-1,4,5-triphenyl-1H-imidazole, C22H18N2, the three substituent phenyl groups are not delocalized with the imidazole moiety; the dihedral angles these phenyl groups form with the imidazole ring are in the range 2

Clay supported titanium catalyst for the solvent free synthesis of tetrasubstituted imidazoles and benzimidazoles

A series of clay supported metal containing catalysts were prepared and their catalytic performance was evaluated in the synthesis of tetrasubstitued imidazoles under solvent free condition. It was found that K10 supported titanium catalyst showed higher activity compared to other catalysts. The catalysts were characterized by FTIR, XRD, TG/DTA, BET surface area and SEM. The general applicability of the method was demonstrated for the synthesis of tetra- substituted imidazoles from aldehydes and amines containing various electron donating and electron withdrawing substituents. The diversity of the catalyst was studied by synthesis of benzimidazoles and quinoxalines. The mechanism of formation of the products is explained in detail. The catalyst was found to be active for three cycles.