24512-63-8

Basic information

• Product Name: Geniposide
• Synonyms: GENIPOSIDE;Methyl (1R,2S,6S)-9-(hydroxymethyl)-2-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-3-oxabicyclo[4.3.0]nona-4,8-diene-5-carboxylate;glucopyranosyloxy)-1,4a,5,7a-tetrahydro-7-(hydroxymethyl)-,methyl ester, (1S,4aS,7aS)-;(1S)-1α-(β-D-Glucopyranosyloxy)-1,4aα,5,7aα-tetrahydro-7-hydroxymethylcyclopenta[c]pyran-4-carboxylic acid methyl ester;1α-(β-D-Glucopyranosyloxy)-1,4aα,5,7aα-tetrahydro-7-(hydroxymethyl)cyclopenta[c]pyran-4-carboxylic acid methyl ester;Geniposide ,98%;Olea europaea L;Geniposidic
• CAS NO: 24512-63-8
• Molecular Formula: C₁₇H₂₄O₁₀
• Molecular Weight: 388.37
• Product Categories: Iridoids;Standard extract;Natural Plant Extract;Glucagon receptor and related;chemical reagent;pharmaceutical intermediate;phytochemical;reference standards from Chinese medicinal herbs (TCM).;standardized herbal extract;Inhibitors
• Mol File: 24512-63-8.mol
• Article Data: 6

Chemical Properties

• Melting Point: 160.0 to 164.0 °C
• Boiling Point: 693.7 °C at 760 mmHg
• Flash Point: 251.3 °C
• Appearance: white to beige/
• Density: 1.59 g/cm³
• Storage Temp.: ?20°C
• Solubility: H2O: ≥5mg/mL
• PKA: 12.80±0.70(Predicted)
• CAS DataBase Reference: Geniposide(CAS DataBase Reference)
• NIST Chemistry Reference: Geniposide(24512-63-8)
• EPA Substance Registry System: Geniposide(24512-63-8)

Safety Data

• Safety Statements: 24/25
• WGK Germany: 3
• Hazardous Substances Data: 24512-63-8(Hazardous Substances Data)

Usage

Pharmacological effects

Geniposide, also known as Gardenia glycosides, geniposide. It is a brown to white crystalline powder, with little flavor and no bitter taste, a cycloolefin ether glycoside compound extracted from the dry and ripe fruit of Rubiaceae Gardenia. Geniposide has a significant role in promoting bile secretion, and can reduce blood bilirubin, as well as promote rapid excretion of bilirubin in the blood. It has an inhibitory effect on Streptococcus hemolyticus and skin fungi. It also has antipyretic, analgesic, sedative, antihypertensive and hemostatic effects. Geniposide has the function of purging pathogenic fire and eliminating restlessness, clearing heat and eliminating damp, decreasing swellinging to relieving pain. The Indications of Geniposide are heat disease, dysphoria, coma delirium, jaundice, heat stranguria, heat in blood, swelling and pain of eye, pathopyretic ulcer, and sprain.

Chemical Properties

White powder

Uses

Geniposide is an iridoid glycoside isolated from the fruit of Gardenia jasminoides Ellis. Geniposide is one of the biologically active ingredients of gardenia fruit. Geniposide is widely used in multi-component injection in the treatment of cerebrovascula

General Description

This substance is a primary reference substance with assigned absolute purity (considering chromatographic purity, water, residual solvents, inorganic impurities). The exact value can be found on the certificate. Produced by PhytoLab GmbH & Co. KG

Biochem/physiol Actions

Geniposide is an iridoid glycoside with a variety of biological activities including neuroprotective, anti-diabetic, antiproliferative, and antioxidative activity. Geniposide has been shown to regulate Nrf2 translocation and upregulate downstream antioxidant protein HO-1 expression through the PI3K/Akt signaling pathway, which may account for its neuroprotective and antioxidative activity. Glucagon-like peptide 1 (GLP-1) receptor may also play a critical role in geniposide induced HO-1 expression.

Synthetic route

diazomethane (186581-53-3, 908094-01-9) + geniposidic acid (27741-01-1) → geniposide (24512-63-8)

10-O-(5-phenyl-2,4-pentadienoyl)-geniposide → geniposide (24512-63-8) + (2E,4E)-methyl 5-phenylpenta-2,4-dienoate (38447-05-1, 38448-84-9, 101934-35-4, 121411-05-0, 1516-24-1, 24196-39-2)

Conditions	Yield
With water In methanol for 1h; Ambient temperature;

geniposidic acid (27741-01-1) + diazomethyl-trimethyl-silane (18107-18-1) → geniposide (24512-63-8)

Conditions	Yield
In methanol; hexane; chloroform at 20℃; for 1.5h; Inert atmosphere;	18.4 mg

methyl (1R,4aS,7aS)-1-Hydroxy-7-((pivaloyloxy)-methyl)-1,4a,5,7a-tetrahydrocyclopenta[c]pyran-4-carboxylate → geniposide (24512-63-8)

Conditions	Yield
Multi-step reaction with 2 steps 1: trimethylsilyl trifluoromethanesulfonate / dichloromethane / 3.5 h / -30 - 20 °C / Molecular sieve; Inert atmosphere 2: sodium methylate / methanol / 3 h / 50 °C View Scheme

7-(2,2-dimethyl-propionyloxymethyl)-1-(3,4,5-triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-yloxy)-1,4a,5,7a-tetrahydro-cyclopenta[c]pyran-4-carboxylic acid methyl ester (1141938-70-6) → geniposide (24512-63-8)

Conditions	Yield
With sodium methylate In methanol at 50℃; for 3h;

genipin (70094-79-0, 73610-59-0, 6902-77-8) → geniposide (24512-63-8)

Conditions	Yield
Multi-step reaction with 3 steps 1: pyridine / dichloromethane / 0 - 20 °C / Inert atmosphere 2: trimethylsilyl trifluoromethanesulfonate / dichloromethane / 3.5 h / -30 - 20 °C / Molecular sieve; Inert atmosphere 3: sodium methylate / methanol / 3 h / 50 °C View Scheme

O-[(α-D-mannopyranosyl)-(1->6)-(α-D-mannopyranosyl)-(1->3)-β-D-mannopyranosyl]-(1->4)-(1,2-dideoxy-α-D-glucopyrano)-[2,1-d]-2-methyloxazoline (861695-58-1) + geniposide (24512-63-8) → C43H67NO30 (1093135-91-1)

Conditions	Yield
With endo-β-N-acetylglucosaminidase from Arthrobactor protophormiae In dimethyl sulfoxide at 23℃; for 2h; pH=7.0; aq. phosphate buffer; Enzymatic reaction;	100%

geniposide (24512-63-8) → geniposidic acid (27741-01-1)

Conditions	Yield
With lithium hydroxide In methanol at 50℃;	90%
With sodium hydroxide at 60℃; for 1h;
With water; sodium hydroxide at 60℃; for 1.5h; Concentration;
With sodium hydroxide at 60℃; for 2h;

geniposide (24512-63-8) → genipin (70094-79-0, 73610-59-0, 6902-77-8)

Conditions	Yield
With water In dichloromethane at 37℃; for 24h; Enzymatic reaction;	84%
With immobilized β-glucosidase In ethyl acetate at 55℃; pH=4.5; aq. acetate buffer;	63.08%
With acetate buffer; β-glucosidase at 37℃; for 5h; pH=5.0;	0.5 g

geniposide (24512-63-8) + benzyl bromide (100-39-0) → 7-benzyl-1-(3,4,5,6-tetrabenzyl)geniposide

Conditions	Yield
Stage #1: geniposide With sodium hydride In N,N-dimethyl-formamide; mineral oil for 1h; Cooling with ice; Stage #2: benzyl bromide In N,N-dimethyl-formamide; mineral oil at 20℃;	70%
Stage #1: geniposide With sodium hydride In N,N-dimethyl-formamide for 1h; Cooling with ice; Stage #2: benzyl bromide In N,N-dimethyl-formamide at 20℃;	42%
Stage #1: geniposide With sodium hydride In N,N-dimethyl-formamide for 1h; Cooling with ice; Stage #2: benzyl bromide In N,N-dimethyl-formamide at 20℃;	42%

geniposide (24512-63-8) + 2-Methoxypropene (116-11-0) + 2,2-dimethoxy-propane (77-76-9) → 4',6'-isopropylidene-10-O-(1-methyl-1-methoxyethyl)-geniposide (256221-80-4) + 2',3':4',6'-di-O-isopropylidene-10-O-(1-methyl-1-methoxyethyl)-geniposide (256221-82-6)

Conditions	Yield
Stage #1: geniposide; 2,2-dimethoxy-propane With pyridinium p-toluenesulfonate In acetone at 20 - 50℃; Substitution; Stage #2: 2-Methoxypropene In acetone at 20 - 50℃; Substitution;	A 55% B 22%

geniposide (24512-63-8) + trityl chloride (76-83-5) → (1S,4aS,7aS)-7-Hydroxymethyl-1-((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-trityloxymethyl-tetrahydro-pyran-2-yloxy)-1,4a,5,7a-tetrahydro-cyclopenta[c]pyran-4-carboxylic acid methyl ester + (1S,4aS,7aS)-1-((2S,3R,4S,5S,6R)-3,4,5-Trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-7-trityloxymethyl-1,4a,5,7a-tetrahydro-cyclopenta[c]pyran-4-carboxylic acid methyl ester (265096-97-7)

Conditions	Yield
With pyridine at 20℃; tritylation;	A 14% B 37%

geniposide (24512-63-8) → D-Glucose (2280-44-6) + genipin (70094-79-0, 73610-59-0, 6902-77-8)

Conditions	Yield
With β-glucosidase In water at 37℃; for 2h;

geniposide (24512-63-8) → (1S,4aS,7aS)-1-[(S)-2-Hydroxy-1-(2-hydroxy-1-hydroxymethyl-ethoxy)-ethoxy]-7-hydroxymethyl-1,4a,5,7a-tetrahydro-cyclopenta[c]pyran-4-carboxylic acid methyl ester

Conditions	Yield
With sodium tetrahydroborate; sodium periodate 1.) RT, 2 h, 2.) RT, 2 h; Multistep reaction;

geniposide (24512-63-8) → 10-deoxygeniposide (52584-79-9)

Conditions	Yield
With perchloric acid; hydrogen; palladium on activated charcoal In methanol	312.3 mg

geniposide (24512-63-8) + acetic anhydride (108-24-7) → geniposide penta-acetate (49776-64-9)

Conditions	Yield
In pyridine Ambient temperature;

geniposide (24512-63-8) + benzaldehyde (100-52-7) → 4',6'-O-benzylidene-geniposide (78924-52-4)

Conditions	Yield
With zinc(II) chloride Ambient temperature;	26.26 g

geniposide (24512-63-8) → C17H25(2)HO10 + C17H25(2)HO10

Conditions	Yield
With triethylamine; deuterium; palladium on activated charcoal Reduction; Title compound not separated from byproducts;

geniposide (24512-63-8) + 2,2-dimethoxy-propane (77-76-9) → 4',6'-O-isopropylidene-geniposide + 2',3':4',6'-di-O-isopropylidene-geniposide + 4',6'-isopropylidene-10-O-(1-methyl-1-methoxyethyl)-geniposide (256221-80-4) + 10,6'-di-O-(1-methoxy-1-methylethyl)-geniposide + 2',3':4',6'-di-O-isopropylidene-10-O-(1-methyl-1-methoxyethyl)-geniposide

Conditions	Yield
With pyridinium p-toluenesulfonate In acetone at 20℃; for 36h; Substitution;	A n/a B 0.17 g C 8.08 g D 0.35 g E n/a

geniposide (24512-63-8) → geniposidic acid aglucone

Conditions	Yield
Multi-step reaction with 2 steps 1: aq. NaOH / 1 h / 60 °C 2: cellulase / H2O / 18 h / 50 °C / pH 4.0 View Scheme

geniposide (24512-63-8) → (1S,4aS,7R,7aS)-7-Acetoxymethyl-1-((2S,3R,4S,5R,6R)-3,4,5-triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-yloxy)-1,4a,5,6,7,7a-hexahydro-cyclopenta[c]pyran-4-carboxylic acid methyl ester (42830-28-4)

Conditions	Yield
Multi-step reaction with 5 steps 1: 37 percent / pyridine / 20 °C 2: 16.0 mg / pyridine 3: 76 percent / 80 percent aq. AcOH / 0.67 h / 80 °C 4: 50 percent / H2 / PtP2 / ethanol / 20 °C 5: 88 percent / pyridine View Scheme

geniposide (24512-63-8) → 6,7-dihydroapodantheroside pentaacetate (42830-25-1)

Conditions	Yield
Multi-step reaction with 5 steps 1: 37 percent / pyridine / 20 °C 2: 16.0 mg / pyridine 3: 76 percent / 80 percent aq. AcOH / 0.67 h / 80 °C 4: 23 percent / H2 / PtP2 / ethanol / 20 °C 5: 80 percent / pyridine View Scheme

geniposide (24512-63-8) → (1S,4aS,7aS)-7-Hydroxymethyl-1-((2S,3R,4S,5R,6R)-3,4,5-triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-yloxy)-1,4a,5,7a-tetrahydro-cyclopenta[c]pyran-4-carboxylic acid methyl ester (54621-24-8)

Conditions	Yield
Multi-step reaction with 3 steps 1: 37 percent / pyridine / 20 °C 2: 16.0 mg / pyridine 3: 76 percent / 80 percent aq. AcOH / 0.67 h / 80 °C View Scheme

geniposide (24512-63-8) → (1S,4aS,7R,7aS)-7-Hydroxymethyl-1-((2S,3R,4S,5R,6R)-3,4,5-triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-yloxy)-1,4a,5,6,7,7a-hexahydro-cyclopenta[c]pyran-4-carboxylic acid methyl ester (265097-02-7)

Conditions	Yield
Multi-step reaction with 4 steps 1: 37 percent / pyridine / 20 °C 2: 16.0 mg / pyridine 3: 76 percent / 80 percent aq. AcOH / 0.67 h / 80 °C 4: 50 percent / H2 / PtP2 / ethanol / 20 °C View Scheme

geniposide (24512-63-8) → (1S,4aS,7S,7aS)-7-Hydroxymethyl-1-((2S,3R,4S,5R,6R)-3,4,5-triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-yloxy)-1,4a,5,6,7,7a-hexahydro-cyclopenta[c]pyran-4-carboxylic acid methyl ester (265097-01-6)

Conditions	Yield
Multi-step reaction with 4 steps 1: 37 percent / pyridine / 20 °C 2: 16.0 mg / pyridine 3: 76 percent / 80 percent aq. AcOH / 0.67 h / 80 °C 4: 23 percent / H2 / PtP2 / ethanol / 20 °C View Scheme

geniposide (24512-63-8) → 10-O-benzoyladoxoside tetraacetate

Conditions	Yield
Multi-step reaction with 5 steps 1: 37 percent / pyridine / 20 °C 2: 16.0 mg / pyridine 3: 76 percent / 80 percent aq. AcOH / 0.67 h / 80 °C 4: 23 percent / H2 / PtP2 / ethanol / 20 °C 5: 100 percent / pyridine / 20 °C View Scheme

geniposide (24512-63-8) → (1S,4aS,7aS)-7-Acetoxymethyl-1-((2S,3R,4S,5R,6R)-3,4,5-triacetoxy-6-trityloxymethyl-tetrahydro-pyran-2-yloxy)-1,4a,5,7a-tetrahydro-cyclopenta[c]pyran-4-carboxylic acid methyl ester

Conditions	Yield
Multi-step reaction with 2 steps 1: 14 percent / pyridine / 20 °C 2: pyridine View Scheme

geniposide (24512-63-8) → (1S,4aS,7aS)-1-((2S,3R,4S,5R,6R)-3,4,5-Triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-yloxy)-7-trityloxymethyl-1,4a,5,7a-tetrahydro-cyclopenta[c]pyran-4-carboxylic acid methyl ester (265096-99-9)

Conditions	Yield
Multi-step reaction with 2 steps 1: 37 percent / pyridine / 20 °C 2: 16.0 mg / pyridine View Scheme

geniposide (24512-63-8) → 6,7-dihydroapodantheroside (42830-26-2)

Conditions	Yield
Multi-step reaction with 2 steps 1.1: 8.08 g / pyridinium p-toluenesulfonate / acetone / 36 h / 20 °C 2.1: Et3N; H2 / Pd/C / ethanol / 4.5 h 2.2: 69 percent / aq. HOAc / 3 h / 45 - 50 °C View Scheme

geniposide (24512-63-8) → (4S,4aS,7S,7aR)-4-Hydroxy-7-hydroxymethyl-hexahydro-cyclopenta[c]pyran-3-one (256221-89-3)

Conditions	Yield
Multi-step reaction with 2 steps 1: 8.08 g / pyridinium p-toluenesulfonate / acetone / 36 h / 20 °C View Scheme

geniposide (24512-63-8) → (S)-1-((1S,2R,3S)-2,3-Bis-hydroxymethyl-cyclopentyl)-ethane-1,2-diol (256221-90-6)

Conditions	Yield
Multi-step reaction with 3 steps 1: 8.08 g / pyridinium p-toluenesulfonate / acetone / 36 h / 20 °C 3: 93 percent / NaBH4 / ethanol / 2.5 h / 20 °C View Scheme
Multi-step reaction with 2 steps 1: 8.08 g / pyridinium p-toluenesulfonate / acetone / 36 h / 20 °C View Scheme
Multi-step reaction with 3 steps 1.1: 8.08 g / pyridinium p-toluenesulfonate / acetone / 36 h / 20 °C 2.1: Et3N; H2 / Pd/C / ethanol / 4.5 h 2.2: 69 percent / aq. HOAc / 3 h / 45 - 50 °C 3.1: O3 / CH2Cl2; methanol / 0.5 h / -78 °C 3.2: 70 percent / NaBH4 / CH2Cl2; methanol; ethanol / -78 - 20 °C View Scheme

geniposide (24512-63-8) → [(1R,2S,5S)-2-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-5-hydroxymethyl-cyclopentyl]-methanol (256221-91-7)

Conditions	Yield
Multi-step reaction with 4 steps 1: 8.08 g / pyridinium p-toluenesulfonate / acetone / 36 h / 20 °C 3: 93 percent / NaBH4 / ethanol / 2.5 h / 20 °C 4: 81 percent / pyridinium p-toluenesulfonate; CuSO4 / acetone / 6 h View Scheme
Multi-step reaction with 3 steps 1: 8.08 g / pyridinium p-toluenesulfonate / acetone / 36 h / 20 °C 3: 81 percent / pyridinium p-toluenesulfonate; CuSO4 / acetone / 6 h View Scheme
Multi-step reaction with 4 steps 1.1: 8.08 g / pyridinium p-toluenesulfonate / acetone / 36 h / 20 °C 2.1: Et3N; H2 / Pd/C / ethanol / 4.5 h 2.2: 69 percent / aq. HOAc / 3 h / 45 - 50 °C 3.1: O3 / CH2Cl2; methanol / 0.5 h / -78 °C 3.2: 70 percent / NaBH4 / CH2Cl2; methanol; ethanol / -78 - 20 °C 4.1: 81 percent / pyridinium p-toluenesulfonate; CuSO4 / acetone / 6 h View Scheme

geniposide (24512-63-8) → [(1S,2R,5S)-2-(6-Amino-purin-9-ylmethyl)-5-hydroxymethyl-cyclopentyl]-methanol

Conditions	Yield
Multi-step reaction with 9 steps 1.1: 8.08 g / pyridinium p-toluenesulfonate / acetone / 36 h / 20 °C 3.1: 93 percent / NaBH4 / ethanol / 2.5 h / 20 °C 4.1: 81 percent / pyridinium p-toluenesulfonate; CuSO4 / acetone / 6 h 5.1: NaH / tetrahydrofuran / 0 - 20 °C 5.2: Bu4NI / tetrahydrofuran / 20 °C 6.1: 1.86 g / aq. HCl / tetrahydrofuran / 24 h / 20 °C 7.1: H5IO6 / tetrahydrofuran / 0.25 h / 20 °C 7.2: K2CO3 / methanol / 4 h / 20 °C 7.3: 94 percent / NaBH4 / methanol / 16 h 8.1: 68.5 percent / Ph3P; DEAD / dioxane / 19 h / 20 °C 9.1: 97 percent / BCl3 / CH2Cl2 / -78 - -25 °C View Scheme
Multi-step reaction with 9 steps 1.1: 8.08 g / pyridinium p-toluenesulfonate / acetone / 36 h / 20 °C 2.1: Et3N; H2 / Pd/C / ethanol / 4.5 h 2.2: 69 percent / aq. HOAc / 3 h / 45 - 50 °C 3.1: O3 / CH2Cl2; methanol / 0.5 h / -78 °C 3.2: 70 percent / NaBH4 / CH2Cl2; methanol; ethanol / -78 - 20 °C 4.1: 81 percent / pyridinium p-toluenesulfonate; CuSO4 / acetone / 6 h 5.1: NaH / tetrahydrofuran / 0 - 20 °C 5.2: Bu4NI / tetrahydrofuran / 20 °C 6.1: 1.86 g / aq. HCl / tetrahydrofuran / 24 h / 20 °C 7.1: H5IO6 / tetrahydrofuran / 0.25 h / 20 °C 7.2: K2CO3 / methanol / 4 h / 20 °C 7.3: 94 percent / NaBH4 / methanol / 16 h 8.1: 68.5 percent / Ph3P; DEAD / dioxane / 19 h / 20 °C 9.1: 97 percent / BCl3 / CH2Cl2 / -78 - -25 °C View Scheme

geniposide (24512-63-8) → [(1S,2S,5S)-2-(6-Amino-purin-9-ylmethyl)-5-hydroxymethyl-cyclopentyl]-methanol

Conditions	Yield
Multi-step reaction with 10 steps 1: 8.08 g / pyridinium p-toluenesulfonate / acetone / 36 h / 20 °C 3: 93 percent / NaBH4 / ethanol / 2.5 h / 20 °C 4: 81 percent / pyridinium p-toluenesulfonate; CuSO4 / acetone / 6 h 5: pyridine / CH2Cl2 / 4 - 20 °C 6: 1.47 g / aq. HCl / tetrahydrofuran / 34 h / 20 °C 7: H5IO6 / tetrahydrofuran / 0.5 h / 20 °C 8: 0.48 g / NaBH4 / CH2Cl2; ethanol / -78 - 20 °C 9: Ph3P; DEAD / tetrahydrofuran / 12 h / 20 °C 10: 35 percent / liq. NH3 / 72 h / 45 - 50 °C View Scheme
Multi-step reaction with 10 steps 1.1: 8.08 g / pyridinium p-toluenesulfonate / acetone / 36 h / 20 °C 2.1: Et3N; H2 / Pd/C / ethanol / 4.5 h 2.2: 69 percent / aq. HOAc / 3 h / 45 - 50 °C 3.1: O3 / CH2Cl2; methanol / 0.5 h / -78 °C 3.2: 70 percent / NaBH4 / CH2Cl2; methanol; ethanol / -78 - 20 °C 4.1: 81 percent / pyridinium p-toluenesulfonate; CuSO4 / acetone / 6 h 5.1: pyridine / CH2Cl2 / 4 - 20 °C 6.1: 1.47 g / aq. HCl / tetrahydrofuran / 34 h / 20 °C 7.1: H5IO6 / tetrahydrofuran / 0.5 h / 20 °C 8.1: 0.48 g / NaBH4 / CH2Cl2; ethanol / -78 - 20 °C 9.1: Ph3P; DEAD / tetrahydrofuran / 12 h / 20 °C 10.1: 35 percent / liq. NH3 / 72 h / 45 - 50 °C View Scheme

Upstream product

• 70094-79-0 genipin 
• 1141938-70-6 7-(2,2-dimethyl-propionyloxymethyl)-1-(3,4,5-triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-yloxy)-1,4a,5,7a-tetrahydro-cyclopenta[c]pyran-4-carboxylic acid methyl ester 
• 27741-01-1 geniposidic acid 
• 18107-18-1 diazomethyl-trimethyl-silane 
• 186581-53-3 diazomethane 

Downstream Products

• 27741-01-1 geniposidic acid 
• 49776-64-9 geniposide penta-acetate 
• 2280-44-6 D-Glucose 
• 70094-79-0 genipin 
• 492-61-5 β-D-glucose 
• 69977-52-2 1-methoxygenipin 
• 42830-27-3 (1S,4aS,7R,7aS)-7-Hydroxymethyl-1-((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-1,4a,5,6,7,7a-hexahydro-cyclopenta[c]pyran-4-carboxylic acid methyl ester 
• 42830-26-2 6,7-dihydroapodantheroside 
• 485-43-8 iridomyrmecin 
• 21651-62-7 nepetalactone 
• 60419-55-8 (+)-teucriumlactone 
• 21699-53-6 isodihydronepetalactol 
• 141887-70-9 2',3',4'-triacetyl-6'-trityl-10-deoxygeniposide 

Relevant articles and documents

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