24523-60-2Relevant academic research and scientific papers
Mechanistic Study on C-C Bond Formation of a Nickel(I) Monocarbonyl Species with Alkyl Iodides: Experimental and Computational Investigations
Yoo, Changho,Ajitha, Manjaly J.,Jung, Yousung,Lee, Yunho
, p. 4305 - 4311 (2015)
An open-shell reaction of the nickel(I) carbonyl species (PNP)Ni-CO (1) with iodoalkanes has been explored experimentally and theoretically. The initial iodine radical abstraction by a nickel(I) carbonyl species was suggested to produce (PNP)Ni-I (4) and
Connection of metallamacrocycles via dynamic covalent chemistry: A versatile method for the synthesis of molecular cages
Granzhan, Anton,Schouwey, Clement,Riis-Johannessen, Thomas,Scopelliti, Rosario,Severin, Kay
scheme or table, p. 7106 - 7115 (2011/06/26)
A modular approach for the synthesis of cage structures is described. Reactions of [(arene)RuCl2]2 [arene = p-cymene, 1,3,5-C6H3Me3, 1,3,5-C6H 3(i-Pr)3] with formylsub
Photolysis of 1,1,1-Triarylalkane. A New Photochemical Carbene Generation Process
Shi, Min,Okamoto, Yoshiki,Takamuku, Setsuo
, p. 3821 - 3824 (2007/10/02)
Upon UV irradiation in methanol some 1,1,1-triarylalkanes underwent an α,α-elimination of two aryl groups to give biaryls and the corresponding carbene intermediates, which inserted into the OH bond of the methanol to afford methyl ethers and/or underwent a 1,2-H shift to afford olefins.Furthermore, the efficieny of this elimination was highly dependent upon the bulkiness of the alkyl groups.
Photolysis of 1,1,1-triphenylalkanes
Shi,Okamoto,Takamuku
, p. 6709 - 6712 (2007/10/02)
Photolysis of 1,1,1-triphenylalkane in methanol gave biphenyl, 1-methoxy-1-phenylalkane, and 1-phenylalkene. The generation of the carbene intermediate by photo α,α-elimination of two phenyl groups was presumed.
THE REACTION OF CARBANIONS WITH TERT-BUTYL RADICALS
Russell, Glen A.,Khanna, Rajive K.
, p. 4133 - 4146 (2007/10/02)
The SRNl free radical chain reaction of Me3CHgCl with nitronate -O2N=C(R1)(R2)> and phenone enolate -)=C(R1)(R2)> anions yields the C-alkylation products 1)(R2)NO2, PhCOC(R1)(R2)CMe3>.Competitive reactions between pairs of anions demonstrate that as the basicity of the anion increases the reactivity toward Me3Cat first increases and then decreases.An inverted reactivity order is also observed with phenylacetonitrile anions.In early transition state reactions, the nucleophilic character of the tert-butyl radical apparently controls the reactivity by virtue of a transition state involving transfer of the electron from radical to the LUMO of the resonance stabilized anion.
