24533-89-9

Basic information

• Product Name: (acrylonitrile)di(phosphine)platinum(O)
• Synonyms: (acrylonitrile)di(phosphine)platinum(O)
• CAS NO: 24533-89-9
• Molecular Weight: 772.725
• Mol File: 24533-89-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (acrylonitrile)di(phosphine)platinum(O)(CAS DataBase Reference)
• NIST Chemistry Reference: (acrylonitrile)di(phosphine)platinum(O)(24533-89-9)
• EPA Substance Registry System: (acrylonitrile)di(phosphine)platinum(O)(24533-89-9)

Safety Data

• Hazardous Substances Data: 24533-89-9(Hazardous Substances Data)

Upstream product

• 16940-66-2 sodium tetrahydroborate 
• 10199-34-5 cis-dichlorobis(triphenylphosphine)platinum(II) 
• 12120-15-9 ethylenebis(triphenylphosphine)platinum⁽⁰⁾ 
• 107-13-1 acrylonitrile 

Relevant articles and documents

Synthesis and characterization of platinum(0) alkene complexes; X-ray crystal structure determinations on [Pt(trans-PhCH=CHCHO)(PPh3)2] and [Pt(trans-PhCH=CHCOMe)(PPh3)2]

Reaction of [Pt(C2H4)(PPh3)2] with a range of alkenes gave the complexes [Pt(alkene)(PPh3)2]. Complexes of alkenes bearing electron-withdrawing ligands were, predictably, more stable than those of electron-rich alkenes. The complexes were characterized by multinuclear (1H, 13C, 31P and 195Pt) NMR spectroscopy and the structures of the derivatives of trans-PhCH=CHCHO and trans-PhCH=CHCOMe were established by X-ray diffraction studies. The complexes reacted with PCy3 to give [Pt(alkene)(PCy3)(PPh3)], usually as a mixture of regioisomers. Copyright