24561-37-3

Upstream product

• 122081-18-9 HONC(CH₃)C(CH₃)NNHC(O)C₆H₄Cl-p 
• 536-40-3 4-chlorobenzoic acid hydrazide 
• 116354-02-0 4-Chloro-benzoic acid 4,5-dimethyl-[1,2,3]triazol-1-yl ester 
• 14941-17-4 Butane-2,3-dione monooximate anion 
• 6264-29-5 4-nitrophenyl 4-chlorobenzoate 
• 122081-26-9 C₁₈H₁₅Cl₂N₃O₃ 

Relevant academic research and scientific papers

The effect of acyl substituents on the α-effect: Contrasting α-effect profiles for reactions of 4-nitrophenyl substituted benzoates with neutral and anionic nucleophiles

The magnitude of the α-effect for reactions of 4-nitrophenyl substituted benzoates with a pair of anionic nucleophiles is independent of the electronic nature of the acyl substituent, while the one for the corresponding reactions with a pair of neutral nucleophiles increases as the acyl substituent changes from a strong electron withdrawing substituent to electron donating ones.

Synthesis, structure, and acylating properties of 1-aroyloxy-4,5-dimethyl- 1,2,3-triazoles

Lead tetra-acetate oxidation of α-hydroxyimino aroylhydrazones of biacetyl (1) gives 1-aroyloxy-4,5-dimethyl-1,2,3-triazoles (2), the structures of which were confirmed by X-ray analysis. A mechanism for this reaction is discussed. The products (2) are effective aroylating agents for the amino function under mild conditions.