245756-71-2Relevant academic research and scientific papers
Alkoxy isothiocyanates, RO-N=C=S
Bech, Allan T.,Flammang, Robert,Pedersen, Carl Th.,Wong, Ming Wah,Wentrup, Curt
, p. 1869 - 1873 (1999)
Methoxy isothiocyanate has been identified as a product of pyrolysis of the silver salt of N-methoxydithiocarbamic acid. It is also formed on FVT of 1-(N-methoxythiocarbamoyl)imidazole and 1-(N-methoxythiocarbamoyl)-1,2,4-triazole. Methoxy isothiocyanate was identified by IR spectroscopy in argon matrices at 10 K supported by good agreement with the ab initio and DFT calculated spectrum. Isopropoxy isothiocyanate was generated from the corresponding silver salt in a similar manner. The oligomerization of MeONCS to trithiolanes and tetrathianes is also described.
Alkoxy isothiocyanates as intermediates in the flash vacuum pyrolysis of alkoxythioureas
Pedersen, Carl Th.,Jensen, Frank,Flammang, Robert
experimental part, p. 69 - 74 (2009/07/18)
Methoxy isothiocyanate MeONCS 2b was detected by matrix isolation IR spectroscopy following flash vacuum pyrolysis (FVP) of N-methoxythioureas, N-tert-butyl-N′-methoxythiourea 1d being the best precursor. Isothiocyanates 3, amines, and aldehydes are also
