24612-99-5

Upstream product

• 672-13-9 2-hydroxy-5-methoxybenzaldehyde 
• 96-32-2 bromoacetic acid methyl ester 
• 96-34-4 methyl chloroacetate 

Downstream Products

• 1370710-84-1 methyl 3-acetoxy-3-[2-(carbomethoxymethyloxy)-5-methoxy]phenyl-2-methylenepropanoate 
• 24589-93-3 2-(2-formyl-4-methoxyphenoxy)acetic acid 

Relevant academic research and scientific papers

Morita-Baylis-Hillman route to dimethyl 2,3-Dihydrobenzo[b]oxepine-2,4- dicarboxylates and Methyl 2-(2-carbomethoxybenzo[b]furan-3-yl)propanoates from salicylaldehydes

A new synthetic method for dimethyl 2,3-dihydrobenzo[b]oxepine-2,4- dicarboxylates and methyl 2-(2- carbomethoxybenzo[b]furan-3-yl)propanoates by an intramolecular conjugate displacement reaction or an SN2 reaction of acetates of Morita-Baylis-Hillman adducts of methyl (2-formylphenoxy)acetates has been described.

Benzofuran compounds and their use

Benzofuran compound represented by the formula: STR1 wherein STR2 represents a group capable of releasing a cation in which ....... represents a single or double bond: R1 represents an optionally substituted heterocyclic residue which may be attached to the oxygen atom through a carbon chain; R2 represents a hydrogen atom, a halogen atom, an optionally substituted hydrocarbon residue, an optionally protected hydroxyl group or an optionally protected amino group; Y represents a di- or tri-valent aliphatic hydrocarbon residue having 1 to 8 carbon atoms; and the benzene ring of the benzofuran moiety may have further substituents; or a salt thereof, which has excellent hypoglycemic and hypolipidemic action.