24625-03-4Relevant articles and documents
Nanoreactors stable up to 200 °c: A class of high temperature microemulsions composed solely of ionic liquids
Pei, Yuanchao,Ru, Jie,Yao, Kaisheng,Hao, Lihui,Li, Zhiyong,Wang, Huiyong,Zhu, Xingqi,Wang, Jianji
supporting information, p. 6260 - 6263 (2018/06/22)
It is a challenge to develop microemulsions which can serve as nanoreactors for the synthesis of nanoparticles and chemical reactions at high temperature. In this work, a class of novel high temperature microemulsions consisting solely of ionic liquids have been designed and prepared for the first time. It is found that nanoscale droplets formed in the ionic liquid microemulsions can be maintained up to 200 °C, and the size distribution of the droplets can be easily tuned by selection of the ionic liquids and varying compositions of the systems. By using such microemulsions as nanoreactors, porous metals such as Pt have been prepared at 180 °C without using any purposely added reductant.
Ruthenium catalysts bearing chelating carboxylate ligands: application to metathesis reactions in water
Gawin, Rafa?,Czarnecka, Patrycja,Grela, Karol
scheme or table, p. 1051 - 1056 (2010/03/25)
The novel catalytic system, composed of a ruthenium alkylidene containing a surfactant fragment in the catalysts molecule, is reported. Ring closing metathesis and cross metathesis reactions proceed efficiently in neat water at room temperature, in air, without need of adding an external surfactant.
CATION-ACTIVE 2-HYDROXYETHYL SURFACE-ACTIVE SUBSTANCES. MICELLE FORMATION AND THE CATALYSIS OF NUCLEOPHILIC SUBSTITUTION IN O,O-DIMETHYL O-(p-NITROPHENYL) PHOSPHOROTHIOATE IN ALKALINE SOLUTIONS
Tishkova, E. P.,Federov, S. B.,Kudryavtseva, L. A.,Bel'skii, V. E.,Ivanov, B. E.
, p. 2016 - 2022 (2007/10/02)
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