24632-13-1

Basic information

• Product Name: Cycloheptyl-diphenyl-carbinol
• CAS NO: 24632-13-1
• Molecular Weight: 280.41
• Mol File: 24632-13-1.mol

Chemical Properties

• CAS DataBase Reference: Cycloheptyl-diphenyl-carbinol(CAS DataBase Reference)
• NIST Chemistry Reference: Cycloheptyl-diphenyl-carbinol(24632-13-1)
• EPA Substance Registry System: Cycloheptyl-diphenyl-carbinol(24632-13-1)

Safety Data

• Hazardous Substances Data: 24632-13-1(Hazardous Substances Data)

Upstream product

• 78378-12-8 cycloheptylmagnesium bromide 
• 1460-16-8 cycloheptanoic acid 
• 119-61-9 benzophenone 
• 291-64-5 cycloheptane 
• 107-13-1 acrylonitrile 
• 71-43-2 benzene 
• 24632-04-0 1-p-Toluolsulfonyloxymethyl-1-formyl-cyclohexan 
• 60433-00-3 methyl cycloheptanecarboxylate 

Downstream Products

• 65927-28-8 (diphenylmethylene)cycloheptane 

Relevant articles and documents

Hydrocarbon activation. Synthesis of β-cycloalkyl (Di)nitriles through photosensitized conjugate radical addition

Photoinduced hydrogen abstraction from aliphatic cyclic hydrocarbons (C5 to C7, C12, as well as adamantane) by triplet aromatic ketones in the presence of α,β-unsaturated (di)nitriles offers a straightforward entry to the corresponding alkylated (di)nitriles via the alkyl radicals. Yields are moderate to good depending on the olefins structure (substitution in β slows down the addition to mononitriles, but with α,α-dinitriles electronic activation allows efficient alkylation also of β,β-disubstituted substrates). A tandem alkylation - cyclization process has been obtained with (1-methylpent-4-enylidene)malononitrile.