246509-67-1Relevant articles and documents
Transition metal-catalyzed hetero-[5 + 2] cycloadditions of cyclopropyl imines and alkynes: Dihydroazepines from simple, readily available starting materials
Wender, Paul A.,Pedersen, Torben M.,Scanio, Marc J. C.
, p. 15154 - 15155 (2002)
The first example of a transition metal-catalyzed hetero-[5 + 2] cycloaddition reaction is described. Use of cyclopropyl imines as five-atom components, an alkyne as a two-carbon component, and a Rh(I) catalyst enables a new route to dihydroazepines. This
