246521-95-9Relevant academic research and scientific papers
Stereoselective synthesis of syn-β-amino propargylic ethers: Application to the asymmetric syntheses of (+)-β-conhydrine and (-)-balanol
Louvel, Julien,Chemla, Fabrice,Demont, Emmanuel,Ferreira, Franck,Perez-Luna, Alejandro,Voituriez, Arnaud
, p. 2137 - 2151 (2011/10/12)
The stereoselective synthesis of syn-β-amino propargylic ethers by the addition of racemic lithio 3-(methoxymethoxy)allenylcuprates, and more particularly (cyano) and (mesityl)cuprates, to enantiopure chiral N-tert-butylsulfinylimines is reported. The sco
Asymmetric synthesis of the balanol heterocycle via a palladium-mediated epimerization and olefin metathesis.
Cook,Shanker,Peterson
, p. 615 - 617 (2008/02/12)
[formula: see text] The enantioselective formal synthesis of balanol, a potent protein kinase C inhibitor, was accomplished from D-serine utilizing a Pd-catalyzed equilibration of diastereomeric 5-vinyloxazolines to set the stereochemistry of the vicinal
