2467-52-9Relevant academic research and scientific papers
Elaboration on the Electronics of Salen Manganese Nitrides: Investigations into Alkoxy-Substituted Ligand Scaffolds
Hein, Nicholas M.,Macneil, Gregory A.,Storr, Tim
supporting information, p. 16895 - 16905 (2021/11/18)
The ligand electronics of salen manganese nitride complexes directly influence the locus of oxidation and, thus, the reactivity of the resulting oxidized species. This work investigates the influence of tert-butoxy, isopropoxy, and methoxy substituents on
p-di-t-butoxybenzene
Carman, Raymond M.,Kanizaj, Nicholas,Taylor, Richard J.K.
, p. 515 - 516 (2007/10/03)
p-Di-t-butoxybenzene (1) [p-di-tert-butoxybenzene; benzene, 1,4-di-tert-butoxy-; 1,4-bis(1,1-dimethylethoxy)benzene; 1,4-benzenediol (or benzene-1,4-diol) di-tert-butyl ether; Chem. Abstr. number 15360-01-7] does not have the physical properties ascribed to it in the Dictionary of Organic Compounds, where it has been mistaken for 2,5-di-t-butylhydroquinone (4).
Enantioselective epoxidation of cyclic 1,3-dienes catalyzed by a sterically and electronically optimized (salen)Mn complex
Chang, Sukbok,Heid, Richard M.,Jacobsen, Eric N.
, p. 669 - 672 (2007/10/02)
Chiral (salen)Mn(III)Cl complexes catalyze epoxidation of cyclic 1,3-dienes with moderate-to-good enantioselectivity. A new catalyst (2), bearing sterically hindered and electron donating (OSi(iPr)3 (OTIPS) substituents, induces up to 12% higher selectivity than the previously-reported tert-butyl substituted analog 1.
