246864-32-4Relevant academic research and scientific papers
exo-Glycal approaches to C-linked glycosyl amino acid synthesis
Campbell, Andrew D.,Paterson, Duncan E.,Raynham, Tony M.,Taylor, Richard J.K.
, p. 1599 - 1600 (1999)
Two novel routes to C-linked glycosyl amino acids are described; the first involves elaboration of an exo-glycal and subsequent Ramberg-Backlund rearrangement of a sulfone intermediate to give, after functional group manipulation, a protected C-glycosyl serine, while the second uses hydroboration-Suzuki coupling of the same exo-glycal to produce ultimately the corresponding C-glycosyl asparagine analogue.
