247145-65-9Relevant academic research and scientific papers
Synthesis of amino-sugars using the directed dihydroxylation reaction
Donohoe, Timothy J.,Blades, Kevin,Helliwell, Madeleine
, p. 1733 - 1734 (1999)
The synthesis of protected forms of two amino-sugars, talosamine 1 and allosamine 2, is described; the syn, syn stereochemistry at C-2, C-3 and C-4 was controlled by the use of a hydrogen-bonding directed dihydroxylation reaction using stoichiometric and catalytic OsO4; proof of the relative stereochemistry of the allosamine series was obtained through an X-ray crystal structure of a protected derivative.
