247166-77-4

Upstream product

• 1779-49-3 Methyltriphenylphosphonium bromide 
• 247166-76-3 Diphenylmethyl (2E,4E,7R,12R,13R)-12,13-epoxy-14-oxo-3,5,7-trimethyltetradeca-2,4-dienoate 
• 247166-66-1 (2Z,8R)-8-Methylundec-2-en-10-yn-1-ol 
• 247166-59-2 (6R)-6-Methyl-7-(tetrahydro-2H-pyran-2-yloxy)heptanal 
• 247166-67-2 (2Z,8R,10E)-8,10-Dimethyl-11-iodoundeca-2,10-dien-1-ol 
• 247166-58-1 (7R)-7-Methyl-8-(tetrahydro-2H-pyran-2-yloxy)oct-1-ene 
• 247166-61-6 (2Z,8R)-8-Methyl-9-(tetrahydro-2H-pyran-2-yloxy)non-2-en-1-ol 
• 247166-60-5 Methyl (2Z,8R)-8-methyl-9-(tetrahydro-2H-pyran-2-yloxy)-non-2-enoate 
• 247166-63-8 (2R,7Z)-9-(tert-Butyldiphenylsilyloxy)-2-methylnon-7-en-1-ol 
• 247166-65-0 (2Z,8R)-1-(tert-Butyldiphenylsilyloxy)-8-methylundec-2-en-10-yne 
• 247166-70-7 Diphenylmethyl (2E,4E,7R,12Z)-14-hydroxy-3,5,7-trimethyltetradeca-2,4,12-trienoate 
• 247166-64-9 (2R,7Z)-9-(tert-Butyldiphenylsilyloxy)-2-methyl-1-(p-tolylsulfonyloxy)non-7-ene 

Downstream Products

• 247166-79-6 Diphenylmethyl [2E,4E,7R,(2'R,3'R)]-11-(4'-oxo-3'-vinyl-oxetan-2'-yl)-3,5,7-trimethylundeca-dienoate 
• 29066-42-0 hymeglusin 
• 247166-80-9 Diphenylmethyl [2E,4R/S,5S/R,7R,(2'R,3'R)]-4,5-epoxy-11-(4'-oxo-3'-vinyloxetan-2'-yl)-3,5,7-trimethylundec-2-enoate 
• 247166-81-0 Diphenylmethyl [2E,4R/S,5S/R,7R,(2'R,3'R)]-4,5-epoxy-11-(3'-hydroxymethyl-4'-oxooxetan-2'-yl)-3,5,7-trimethylundec-2-enoate 
• 247166-82-1 Diphenylmethyl [2E,4E,7R,(2'R,3'R)]-11-(3'-hydroxymethyl-4'-oxooxetan-2'-yl)-3,5,7-trimethylundeca-2,4-dienoate 

Relevant academic research and scientific papers

Total synthesis of the cholesterol biosynthesis inhibitor 1233A via a (π-allyl)tricarbonyliron lactone complex

The total synthesis of the β-lactone cholesterol synthase inhibitor 1233A (1) is described employing the oxidative decomplexation of a (π-allyl)tricarbonyliron lactone (2) as the key synthetic step.