247170-65-6

Basic information

• Product Name: (C₅H₅)Ru(CH₂CHCH₂)(P(C₆H₁₁)3)Br⁽¹⁺⁾*PF₆^(1-)=[(C₅H₅)Ru(CH₂CHCH₂)(P(C₆H₁₁)3)Br]PF₆
• CAS NO: 247170-65-6
• Molecular Weight: 712.539
• Mol File: 247170-65-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (C₅H₅)Ru(CH₂CHCH₂)(P(C₆H₁₁)3)Br⁽¹⁺⁾*PF₆^(1-)=[(C₅H₅)Ru(CH₂CHCH₂)(P(C₆H₁₁)3)Br]PF₆(CAS DataBase Reference)
• NIST Chemistry Reference: (C₅H₅)Ru(CH₂CHCH₂)(P(C₆H₁₁)3)Br⁽¹⁺⁾*PF₆^(1-)=[(C₅H₅)Ru(CH₂CHCH₂)(P(C₆H₁₁)3)Br]PF₆(247170-65-6)
• EPA Substance Registry System: (C₅H₅)Ru(CH₂CHCH₂)(P(C₆H₁₁)3)Br⁽¹⁺⁾*PF₆^(1-)=[(C₅H₅)Ru(CH₂CHCH₂)(P(C₆H₁₁)3)Br]PF₆(247170-65-6)

Safety Data

• Hazardous Substances Data: 247170-65-6(Hazardous Substances Data)

Upstream product

• 247064-70-6 [(cyclopentadienyl)bis(acetonitrile)(tricyclohexylphosphine)ruthenium(II)] hexafluorophosphate 
• 106-95-6 allyl bromide 

Relevant articles and documents

[RuCp(PR3)(CH3CN)2]PF6 (R = Ph, Me, Cy). Convenient Precursors for Mixed Ruthenium(II) and Ruthenium(IV) Half-Sandwich Complexes

The reaction of [RuCp(CH3CN)3]PF6 (1) with the monodentate ligands PR3 (R = Me, Ph, Cy) affords the cationic complexes [RuCp(PR3)(CH3CN)2]PF6 (2a-c) in high yields. The CH3-CN exchange kinetics has been studied by NMR, suggesting a dissociative mechanism. Due to van der Waals repulsive interactions between PCy3 and the nitrile ligands, CH3CN is particularly labile in 2c. The chemistry of 2a-c has been further investigated with respect to substitution and oxidative addition.