247237-42-9

Basic information

• Product Name: methyl 6-chloro-2-(N-p-toluenesulfonyl)aminobenzoate
• Synonyms: methyl 6-chloro-2-(N-p-toluenesulfonyl)aminobenzoate
• CAS NO: 247237-42-9
• Molecular Weight: 339.799
• Mol File: 247237-42-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl 6-chloro-2-(N-p-toluenesulfonyl)aminobenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 6-chloro-2-(N-p-toluenesulfonyl)aminobenzoate(247237-42-9)
• EPA Substance Registry System: methyl 6-chloro-2-(N-p-toluenesulfonyl)aminobenzoate(247237-42-9)

Safety Data

• Hazardous Substances Data: 247237-42-9(Hazardous Substances Data)

Upstream product

• 2148-56-3 2-chloro-6-aminobenzoic acid 
• 41632-04-6 methyl 6-chloroanthranilate 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 247237-45-2 methyl 6-chloro-2-[N-(3-ethoxycarbonyl)propyl-N-p-toluenesulfonyl]aminobenzoate 
• 247237-71-4 6-chloro-5-(N-methylamino)-1-[4-[(2-methylbenzoyl)amino]benzoyl]-2,3,4,5-tetrahydro-1H-1-benzazepine 
• 137978-28-0 6-chloro-1-[4-[(2-methylbenzoyl)amino]benzoyl]-5-oxo-2,3,4,5-tetrahydro-1H-1-benzazepine 
• 137984-99-7 6-chloro-1-(4-nitrobenzoyl)-5-oxo-2,3,4,5-tetrahydro-1H-1-benzazepine 
• 137983-88-1 1-(4-aminobenzoyl)-6-chloro-5-oxo-2,3,4,5-tetrahydro-1H-1-benzazepine 
• 247237-53-2 6-chloro-5-oxo-2,3,4,5-tetrahydro-1-p-toluenesulfonyl-1H-1-benzazepine 
• 247237-58-7 6-chloro-5-oxo-2,3,4,5-tetrahydro-1H-1-benzazepine 

Relevant articles and documents

Iodine(III) Reagent-Mediated Intramolecular Amination of 2-Alkenylanilines to Prepare Indoles

A variety of 3-substituted and 2,3-disubstituted indoles were synthesized efficiently in good yields through the intramolecular amination of 2-alkenylanilines promoted by readily available iodine(III) reagents in a short reaction time. Mechanistic studies showed that the reaction pathway went through a nitrenium ion and that 3-acetoxy indoline was the key intermediate in the indole formation. The indole product was easily prepared on a gram scale and amination also proceeded smoothly using catalytic 3,5-dimethylphenyl iodine in the presence of mCPBA. Furthermore, the indolo[3,2-a]carbazole scaffold was prepared in good yield in six steps from commercial ortho-iodoaniline. (Figure presented.).