247255-16-9Relevant academic research and scientific papers
On the unexpected stereochemical outcome of the magnesium in methanol - Conjugate reduction of an exocyclic α,β-unsaturated ester
Gabri?ls, Stefan,Van Haver, Dirk,Vandewalle, Maurits,De Clercq, Pierre,Viterbo, Davide
, p. 1803 - 1809 (2007/10/03)
The conjugate reduction of the exocyclic α,β-unsaturated ester 9 with magnesium in methanol gives a mixture of diastereoisomers containing predominantly the less stable 10a. Eventual structural identification rests on the X-ray diffraction analysis of tosylate 18.
