24743-59-7Relevant academic research and scientific papers
Pyridine-Catalysed Desulfonylative Addition of β-Diketones to Arylazosulfones via Diaziridine Rearrangement
Ji, Xin,Meng, Ling-Guo,Xu, Hailong,Wang, Lei
supporting information, p. 1142 - 1146 (2020/12/31)
A pyridine-catalysed desulfonylative addition of β-diketones to arylazosulfones was developed to obtain diazenyl β-dicarbonyl compounds. The aryldiazenyl group was observed in the desired product from arylazosulfones, and this diazenylation reaction was achieved via a possible rearrangement process based on diaziridine ring cleavage. The scope of the protocol was investigated and a plausible mechanism was given. (Figure presented.).
