247570-26-9

Basic information

• Product Name: 1H-Isoindole-1,3(2H)-dione, 2-(2-naphthalenylmethyl)-
• CAS NO: 247570-26-9
• Molecular Formula: C19H13NO2
• Molecular Weight: 287.318
• Mol File: 247570-26-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1H-Isoindole-1,3(2H)-dione, 2-(2-naphthalenylmethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1H-Isoindole-1,3(2H)-dione, 2-(2-naphthalenylmethyl)-(247570-26-9)
• EPA Substance Registry System: 1H-Isoindole-1,3(2H)-dione, 2-(2-naphthalenylmethyl)-(247570-26-9)

Safety Data

• Hazardous Substances Data: 247570-26-9(Hazardous Substances Data)

Upstream product

• 85-44-9 phthalic anhydride 
• 2018-90-8 naphthalen-2-ylmethylamine 

Downstream Products

• 2018-90-8 naphthalen-2-ylmethylamine 

Relevant articles and documents

Alkoxide-Catalyzed Hydrosilylation of Cyclic Imides to Isoquinolines via Tandem Reduction and Rearrangement

An alkoxide-catalyzed hydrosilylation of cyclic imides to isoquinolines was realized via tandem reduction and rearrangement. Using TMSOK as the catalyst and (EtO)2MeSiH as the reductant, a series of cyclic imides containing different functional groups were reduced to the corresponding 3-aryl isoquinolines in moderate to good yields. The scenario of the reaction pathway was supposed to involve the reduction of imides to ω-hydroxylactams, which underwent rearrangement in the presence of a base catalyst, and then the carbonyl reduction, followed by siloxy elimination.