24779-55-3

Basic information

• Product Name: trans-3-Hydroperoxy-4-vinylcyclohex-1-en
• Synonyms: trans-3-Hydroperoxy-4-vinylcyclohex-1-en
• CAS NO: 24779-55-3
• Molecular Weight: 140.182
• Mol File: 24779-55-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: trans-3-Hydroperoxy-4-vinylcyclohex-1-en(CAS DataBase Reference)
• NIST Chemistry Reference: trans-3-Hydroperoxy-4-vinylcyclohex-1-en(24779-55-3)
• EPA Substance Registry System: trans-3-Hydroperoxy-4-vinylcyclohex-1-en(24779-55-3)

Safety Data

• Hazardous Substances Data: 24779-55-3(Hazardous Substances Data)

Upstream product

• 100-40-3 4-ethenylcyclohexene 

Relevant articles and documents

Autoxidation of Vinylcyclopentane, Vinylcyclohexane, and 4-Vinylcyclohex-1-ene

The title olefins were oxidized with molecular oxygen at 75-80 deg C.About 40percent of the oxygen absorbed were found by iodometric titration as peroxidic oxygen.The reaction products were analyzed by a combination of chemical methods, gas chromatography, and 13C-n.m.r.-spectroscopy.Vinylcyclopentane and vinylcyclohexane are attacked preferably at the tertiary allylic C-H-bonds giving almost equimolar mixtures of the corresponding allylisomeric hydroperoxides.In the case of 4-vinylcyclohex-1-ene the C-H-bonds in position 6 are preferably attacked, but products of attack on the other allylic C-H-bonds also could be identified.In all cases the amount of products which could not be detected gaschromatographically was determined by balance experiments in the presence of an internal standard.