24810-45-5

Upstream product

• 104951-27-1 3-[1-Diethylamino-meth-(Z)-ylidene]-bicyclo[3.1.0]hexan-2-one 

Downstream Products

• 24813-72-7 bicyclo[2.1.0]pentane-2-carboxylic acid methyl ester 
• 24795-44-6 (1R,2R,4R)-Bicyclo[2.1.0]pentane-2-carboxylic acid (4-bromo-phenyl)-amide 
• 24795-44-6 (1R,2S,4R)-Bicyclo[2.1.0]pentane-2-carboxylic acid (4-bromo-phenyl)-amide 
• 24813-72-7 exo-bicyclo<2.1.0>pentane-2-carboxylic acid methyl ester 
• 24813-72-7 endo-bicyclo<2.1.0>pentane-2-carboxylic acid methyl ester 
• 104951-19-1 exo-2-acetylbicyclo<2.1.0>pentane 
• 104951-19-1 endo-2-acetylbicyclo<2.1.0>pentane 
• 26543-59-9 N-methylbicyclo<2.1.0>pentane-2-endo-carbanilide 
• 26543-59-9 N-methylbicyclo<2.1.0>pentane-2-exo-carbanilide 

Relevant academic research and scientific papers

Synthesis of 2-Substituted Bicyclopentanes from Bicyclohexan-2-one

Bicyclohexan-2-one (1) was converted into the 3-diazo derivative (4) wich was ringcontracted thermally to give a variety of amides and esters of bicyclopentane-2-carboxylic acid as exo- and endo-stereoisomers.Conversion of the acids into the corresponding methyl ketones and then Baeyer-Villiger reaction has led to endo- and exo-bicyclopentan-2-yl acetates wich differed markedly in solvolytic reactivity.