24847-15-2

Upstream product

• 90-98-2 4,4'-Dichlorobenzophenone 
• 143-66-8 sodium tetraphenyl borate 
• 100-58-3 phenylmagnesium bromide 

Downstream Products

• 80428-22-4 bis-(4-chloro-phenyl)-phenyl-methane 
• 60586-33-6 C₂₀H₁₆Cl₂O 
• 60586-34-7 C₂₁H₁₈Cl₂O 
• 60586-35-8 (4-Chloro-phenyl)-carbamic acid bis-(4-chloro-phenyl)-phenyl-methyl ester 
• 60586-41-6 5-[Bis-(4-chloro-phenyl)-phenyl-methyl]-benzene-1,2,3-triol 
• 60586-39-2 4-[Bis-(4-chloro-phenyl)-phenyl-methyl]-phenol 
• 60586-45-0 {4-[Bis-(4-chloro-phenyl)-phenyl-methyl]-phenoxy}-acetic acid ethyl ester 
• 60586-46-1 {4-[Bis-(4-chloro-phenyl)-phenyl-methyl]-phenoxy}-acetic acid 
• 60586-44-9 C₂₈H₂₂Cl₂O 
• 60586-43-8 C₂₈H₂₄Cl₂O 
• 60586-42-7 C₂₇H₂₂Cl₂O 
• 60586-40-5 C₂₆H₂₀Cl₂O 

Relevant academic research and scientific papers

Direct allylation of benzyl alcohols, diarylmethanols, and triarylmethanols mediated by XtalFluor-E

We report the direct allylation of benzyl alcohols, diarylmethanols and triarylmethanols mediated by XtalFluor-E using allyltrimethylsilane. The resulting allylated products are obtained in moderate to high yield.

Rhodium-catalyzed addition of arylboron compounds to nitriles, ketones, and imines

The rhodium-catalyzed addition reactions of sodium tetraphenylborate and arylboronic acids to nitriles, ketones, and imines were examined. The reaction of nitriles could be carried out efficiently in the presence of a catalyst system of [RhCl(cod)]2-dppp and H2O to give the corresponding monoarylated products selectively. Although unactivated ketones and imines are known to be poor electrophiles for rhodium-catalyzed arylation, the phenylation of them with use of sodium tetraphenylborate proceeded smoothly in the presence of [RhCl(cod)]2 and Rh(acac)(cod) as catalysts, respectively. The addition of NH4Cl was found to be crucial to effectively conduct the reaction of ketones and imines.