24858-02-4 Usage
Uses
Used in Organic Synthesis:
Vinyl-t-butyldimethylsilane is used as a reagent for the protection of alcohols in organic synthesis, providing a means to temporarily shield the hydroxyl group from unwanted reactions. The TBDMS group's mild removal conditions allow for selective deprotection, facilitating the synthesis of complex organic molecules.
Used in the Synthesis of Complex Organic Molecules:
In the field of complex organic molecule synthesis, vinyl-t-butyldimethylsilane is utilized as a versatile building block. The presence of the vinyl group enables further functionalization, expanding the compound's synthetic applications and contributing to the creation of a diverse range of organic compounds.
Used in Pharmaceutical and Chemical Research:
Vinyl-t-butyldimethylsilane is employed as a key intermediate in the development of new pharmaceuticals and specialty chemicals. Its unique properties allow researchers to explore novel synthetic pathways and construct intricate molecular structures with potential applications in various industries.
Used in Material Science:
In material science, vinyl-t-butyldimethylsilane is used as a precursor in the synthesis of new materials with specific properties. Vinyl-t-butyldimethylsilane's ability to be further functionalized allows for the development of materials with tailored characteristics for use in various applications, such as coatings, adhesives, or polymers.
Check Digit Verification of cas no
The CAS Registry Mumber 24858-02-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,4,8,5 and 8 respectively; the second part has 2 digits, 0 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 24858-02:
(7*2)+(6*4)+(5*8)+(4*5)+(3*8)+(2*0)+(1*2)=124
124 % 10 = 4
So 24858-02-4 is a valid CAS Registry Number.
InChI:InChI=1/C8H18Si/c1-7-9(5,6)8(2,3)4/h7H,1H2,2-6H3
24858-02-4Relevant articles and documents
Conformation Properties of Buta-1,3-diene-1,4-diones (Bisketenes): Computational and Photoelectron Spectroscopic Studies
Werstiuk, Nick H.,Ma, Jiangong,McAllister, Michael A.,Tidwell, Thomas T.,Zhao, Da-chuan
, p. 3383 - 3390 (1994)
The highest occupied molecular orbital (HOMO) energies of a series of monoketenes RCH=C=O with a variety of representative substituents have been calculated by ab initio methods, and give good agreement with available experimental photoelectron ionization energies.The structures and orbital energies of the monoketenes Me3SiCH=C=O (5) and t-BuMe2SiCH=C=O (6), the alkene t-BuMe2SiCH=CH2 (7) and the bisketenes (Me3SiC=C=O)2 (1) and (t-BuMe2SiC=C=O)2 (4) have also been calculated by ab initio methods, and are compared with experimentally measured photoelectron ionization energies.The spectra of the t-BuMe2Si compounds show a characteristic band associated with the t-Bu-Si bond.Comparison of the measured and calculated spectra provides strong evidence that the bisketenes 1 and 4 exist predominantly in twisted conformations, with dihedral angles 105 deg in the former case and 120 deg in the latter.Dipole moment measurements on 1 and 5 confirm the conclusion.
THE SILAPINACOL REARRANGEMENT: CONVERSION OF α,β-DIHYDROXYSILANES INTO α-SILYL CARBONYL COMPOUNDS
Cunico, Robert F.
, p. 4269 - 4272 (2007/10/02)
Treatment of α,β-dihydroxysilanes with trifluoroacetic acid in chloroform results in a 1,2-migration of the silyl group to give α-silyl aldehydes and ketones.The t-butyl-dimethylsilyl compounds can be isolated in high yields.
