24869-00-9Relevant academic research and scientific papers
Synthesis and Reactions of
Kabir, Shariff E.,Howlader, Mohammad B. H.
, p. 47 - 50 (2007/10/02)
The cluster (II), obtained by the reaction of with Me3NO/MeCN, reacts with trifluoroacetic acid to give the singly protonated cation (+) (III), isolated in good yields as the hexafluorophosphate salt and (IV).Cluster-IV undergoes decarbonylation on refluxing in heptane to give .Cluster-II also reacts with triethylphosphine at room temperature to give 1,2-.The cationic cluster PF6 reacts with NEt4CN to give two main isomers of .The compounds have been characterised by IR, NMR and elemental analyses.
