248957-54-2

Basic information

• Product Name: methyl (E)-12-(tert-butyl)dimethylsilyloxy-2-(4-methoxyphenylseleno)dodec-4-enoate
• Synonyms: methyl (E)-12-(tert-butyl)dimethylsilyloxy-2-(4-methoxyphenylseleno)dodec-4-enoate
• CAS NO: 248957-54-2
• Molecular Weight: 527.678
• Mol File: 248957-54-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl (E)-12-(tert-butyl)dimethylsilyloxy-2-(4-methoxyphenylseleno)dodec-4-enoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (E)-12-(tert-butyl)dimethylsilyloxy-2-(4-methoxyphenylseleno)dodec-4-enoate(248957-54-2)
• EPA Substance Registry System: methyl (E)-12-(tert-butyl)dimethylsilyloxy-2-(4-methoxyphenylseleno)dodec-4-enoate(248957-54-2)

Safety Data

• Hazardous Substances Data: 248957-54-2(Hazardous Substances Data)

Upstream product

• 91898-32-7 8-(tert-butyldimethylsiloxy)octan-1-ol 
• 128622-13-9 8-(tert-butyl)dimethylsilyloxyoctanal 
• 38762-70-8 bis(4-methoxyphenyl)diselenide 
• 248957-50-8 methyl (E)-12-(tert-butyl)dimethylsilyloxydodec-4-enoate 

Downstream Products

• 248957-49-5 (E)-12-hydroxy-2-(4-methoxyphenylseleno)dodec-4-enoic acid 
• 248957-53-1 (E)-2-(4-methoxyphenylseleno)dodec-4-en-12-olide 
• 87371-99-1 (3Z)-dodecen-12-olide 
• 248957-55-3 methyl (E)-12-hydroxy-2-(4-methoxyphenylseleno)dodec-4-enoate 

Relevant articles and documents

Organoselenium-assisted route to conjugated dienoic macrolides. Synthesis of (Z)-dodec-3-en-12-olide, a pheromone of the flat grain beetle Cryptolestes pusillus (Coleoptera: Cucujidae)

Oxidative elimination of the arylseleno group in (E)-2-(4-methoxyphenylseleno)dodec-4-en-12-olide gave (2Z,4E)-dodeca-2,4-diene-12-olide which on 1,4-cis-hydrogenation(η6-naphthalene)tricarbonylchromium afforded the title pheromone. (E)-2-(4-Me