249284-53-5Relevant academic research and scientific papers
Synthesis of a highly strained uranacycle: Molecular structures of organometallic products arising from reduction, oxidation and protonolysis
Boaretto, Rita,Roussel, Paul,Alcock, Nathaniel W.,Kingsley, Andrew J.,Munslow, Ian J.,Sanders, Christopher J.,Scott, Peter
, p. 174 - 184 (1999)
The reaction of [U(NN′3)I] [NN′3=N(CH2CH2NSiMe2Bu t)3] with Group 1 and 2 metal alkyls gives, via metalation of a methylsilyl group, a highly strained metallacycle [U(bit-NN′sub
Structure and reactions of a metallacyclic complex containing a remarkably long uranium-carbon bend
Boaretto, Rita,Roussel, Paul,Kingsley, Andrew J.,Munslow, Ian J.,Sanders, Christopher J.,Alcock, Nathaniel W.,Scott, Peter
, p. 1701 - 1702 (2007/10/03)
The intramolecular metalation of a β-silyl methyl group in [U{N(CH2CH2NSiMe2Bu(t))3}(CH2Ph)] occurs rapidly, despite the conformational demands of the triamidoamine ligand, to produce a highly strained metallacycle (U-C ca, 2.75 A); this complex reacts cleanly with a range of carbon and other acids to give, for example, an alkynyl with a bent (156°) U-C≡C unit.
