24929-85-9Relevant academic research and scientific papers
1,n-TRIORGANOSILYL MIGRATIONS IN THE REARRANGEMENTS OF SILYL-SUBSTITUTED ORGANOLITHIUM COMPOUNDS
Eisch, John J.,Tsai, Miin-Rong
, p. 5 - 24 (2007/10/02)
Under the agency of the potent lithiating agent, n-butyllithium in TMEDA, an array of organosilanes was found to undergo 1,n-silyl rearangements via carbanionic intermediates.Unambiguous 1,2-, 1,3- and 1,4-silyl shifts were unconvered in 1-trimethylsilyl-
