24940-43-0

Downstream Products

• 14056-88-3 trans-dichlorobis(triphenylphosphine)platinum(II) 
• 74426-95-2 [N(CH₃)4]⁽¹⁺⁾*[Pt(C₆F₅)3(C₄H₈S)]^(1-)=[N(CH₃)4][Pt(C₆F₅)3(C₄H₈S)] 
• 1211509-94-2 chloro(5,6-dihydro-2,3-diphenyl-5-(pyridin-2-ylimino)pyrrolo[3,4-b]pyrazin-7-ylidene(-1H))platinum(II) 
• 1609079-20-0 C₃₅H₃₈N₃PPt 
• 1609079-21-1 C₃₄H₃₇N₄PPt 
• 1609079-22-2 C₃₇H₃₂F₃N₄PPt 
• 1609079-23-3 C₃₂H₂₉F₃N₃PPt 
• 1609079-25-5 C₃₃H₂₈F₆N₃PPt 
• 1609079-24-4 C₄₀H₃₇F₃N₃PPt 
• 86392-30-5 Pt(C₆Cl₅)2(C₄H₈S)2 
• 910134-29-1 dichloroplatinum(II)((R)-p-tolyl-BINAP 
• 207393-67-7 trans-PtCl(3,5-dichlorotrifluorophenyl)(tetrahydrothiophene)2 

Relevant academic research and scientific papers

Synthesis and Reactivity of Trinuclear Complexes of Platinum containing the Single Bridging Ligand SC4H8. Molecular Structure of 2

Trinuclear complexes of the type 2 (X = Cl, Br, I, or C6F5; SC4H8 = tetrahydrothiophene) (1)-(4) have been prepared from trans- and NBu4 (molar ratio 1:2).The SC4H8 ligands act as the single bridge between the central platinum atom and the two terminal ones.Attempts to prepare similar trinuclear complexes with singly bridging halide ligands failed since the reaction between trans- (py = pyridine) and NBu4 (molar ratio 1:2) does not take place, while trans- or (cod = cyclo-octa-1,5-diene), under similar conditions, yield cis- and 2 or and 2 respectively.The trinuclear derivatives (1) and (3) react with neutral ligands L to give different mononuclear complexes, depending on the ligand L: when L = PPh3, NBu4 and cis-; when L = CO, NBu4 and trans-.The molecular stucture of 2 has been established by a single-crystal X-ray diffraction study.The compound forms triclinic crystals in the space group P1/, with Z = 1 and unit-cell dimensions a = 12.463(3), b = 12.487(3), c = 15.137(3) Angstroem, α = 85.68(15), β = 66.04(2), and γ = 87.04(1) degree.The structure was refined to R = 0.048 and R' = 0.048.The central platinum atom in the trinuclear anion (2-) lies on a crystallographic centre of symmetry and is bonded to two Cl atoms and two S atoms (from two SC4H8 ligands), the latter acting as bridging ligands between the central and the terminal Pt atoms.