24948-33-2Relevant academic research and scientific papers
LiClO4-Catalyzed Nucleophilic Addition to α-Chiral Aldehydes, Aldimines, and Oxiranes
Ipaktschi, Junes,Heydari, Akbar
, p. 1905 - 1912 (2007/10/02)
The diastereoselectivity of lithium perchlorate-induced addition of trimethylsilyl cyanide and O-silylated ketene acetals to α-chiral aldehydes is studied.Whereas aldehyde 1 reacts with the ketene acetal 2 exclusively to form the syn-ester 3, a divergent
