249631-03-6

Basic information

• Product Name: ruthenium(2+) trifluoroacetate - [3-{bis[3-(trifluoromethyl)phenyl]phosphanyl}-2-({bis[3-(trifluoromethyl)phenyl]phosphanyl}methyl)-2-methylpropyl]{bis[3-(trifluoromethyl)phenyl]}phosphane (1:2:1)
• CAS NO: 249631-03-6
• Molecular Formula: C₅₁H₃₃F₂₄O₄P₃Ru
• Molecular Weight: 1359.7583
• Mol File: 249631-03-6.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 753.1°C at 760 mmHg
• Flash Point: 409.2°C
• Vapor Pressure: 1.16E-21mmHg at 25°C
• CAS DataBase Reference: ruthenium(2+) trifluoroacetate - [3-{bis[3-(trifluoromethyl)phenyl]phosphanyl}-2-({bis[3-(trifluoromethyl)phenyl]phosphanyl}methyl)-2-methylpropyl]{bis[3-(trifluoromethyl)phenyl]}phosphane (1:2:1)(CAS DataBase Reference)
• NIST Chemistry Reference: ruthenium(2+) trifluoroacetate - [3-{bis[3-(trifluoromethyl)phenyl]phosphanyl}-2-({bis[3-(trifluoromethyl)phenyl]phosphanyl}methyl)-2-methylpropyl]{bis[3-(trifluoromethyl)phenyl]}phosphane (1:2:1)(249631-03-6)
• EPA Substance Registry System: ruthenium(2+) trifluoroacetate - [3-{bis[3-(trifluoromethyl)phenyl]phosphanyl}-2-({bis[3-(trifluoromethyl)phenyl]phosphanyl}methyl)-2-methylpropyl]{bis[3-(trifluoromethyl)phenyl]}phosphane (1:2:1)(249631-03-6)

Safety Data

• Hazardous Substances Data: 249631-03-6(Hazardous Substances Data)

Upstream product

• 204906-16-1 CH₃C(CH₂P(C₆H₄CF₃)2)3 

Downstream Products

• 249631-12-7 [Ru2(μ-Cl)3(CH3C(CH2P(m-CF3C6H4)2)3)2]Cl 
• 249631-23-0 [RuH(MeCN)2(CH₃C(CH₂P(m-CF₃C₆H₄)2)3)]CF₃SO₃ 
• 207747-34-0 [Ru(MeCN)3(CH₃C(CH₂P(m-CF₃C₆H₄)2)3)](CF₃SO₃)2 

Relevant articles and documents

The ruthenium and iridium coordination chemistry of the tripodal ligand CH3C{CH2P(m-CF3-C6H4)2}3

The ruthenium(II) complexes [Ru(CF3CO2)2(CF3triphos)], [Ru2(μ-Cl)3(CF3triphos)2]Cl, [RuH(CH3CN)2(CF3triphos)](CF3SO3) and (Ru(CH3CN)3(CF3triphos)](CF3SO3)2 (CF3triphos = CH3C{CH2P(m-CF3C6H4)2}3) were prepared and characterized. The iridium complexes [Ir(COD)(CF3triphos)](+), [IrCl(CO)(CF3triphos)], [Ir(CO)2(CF3triphos)](+), [IrCl3(CF3triphos)] and [IrCl3-n(-)(MeCN)n(CF3triphos)](CF3SO3)n (n = 1, 2 and 3) were also prepared and characterized. The coordination chemistries of these two elements withCF3triphos and with the unsubstituted ligand CH3C{CH2P(C6H5)2}3 (Htriph os) are compared. It is shown that, relative to Htriphos, CF3triphos (a)stabilizes the iridium(I) relative to the iridium(III) oxidation state and (b) its cationic complexes are stronger Lewis acids.