24973-57-7Relevant academic research and scientific papers
Electrochemical and Spectroscopic Studies of 3,5-Di-tert-butyl-2-aminophenol and of Electrosynthesized 3,5-Di-tert-butyl-2-iminocyclohexa-3,5-dienone in Aprotic Solvents
Harmalker, Subhash P.,Sawyer, Donald T.
, p. 3579 - 3583 (1984)
In acetonitrile 3,5-di-tert-butyl-2-iminocyclohexa-3,5-dienone (DTBQI) is the major product from the controlled-potential electrooxidation of 3,5-di-tert-butyl-2-aminophenol (DTBAPH2).The same product results from the chemical oxidation of DTBAPH2 by PbO2.The redox chemistry for DTBAPH2, DTBQI, and o-aminophenol in dimethyl sulfoxide and acetonitrile has been studied with cyclic voltammetry and controlled-potential electrolysis, and the products and intermediates have been characterized by 1H and 13C NMR, ESR, IR, and UV-vis spectroscopy.Addition of strong base (OH-) to DTBQI causes it to be reduced to a product with the characteris tics of DTBAPH-.Redox reaction mechanisms are proposed for the electrochemical oxidation of DTBAPH- to DTBQI and for the latter's reduction.
A Novel Bulky Heteroaromatic-Substituted Methanide Mimicking NacNac: Bis(4,6-tert-butylbenzoxazol-2-yl)methanide in s-Block Metal Coordination
Koehne, Ingo,Bachmann, Sebastian,Niklas, Thomas,Herbst-Irmer, Regine,Stalke, Dietmar
, p. 13141 - 13149 (2017)
A novel bulky bis(4,6-tBu-benzoxazol-2-yl)methane ligand was synthesized in a straightforward three-step synthesis. The corresponding complexes [Li{(4,6-tBu-NCOC6H2)2CH}THF], [K{η5-(4,6-tBu-NCOC6Hsub
