249889-32-5Relevant articles and documents
Influence of the presence of heteroatoms in the olefin chain on the Pauson-Khand reaction with metal (Cr, W) carbene enyne complexes
Pares, Joan,Moreto, Josep M.,Ricart, Susagna,Barluenga, Jose,Fananas, Francisco J.
, p. 247 - 253 (1999)
The study of the influence caused by the presence of an heteroatom, either at an internal or terminal site of the olefin, on the outcome of the Pauson-Khand cycloaddition in metal carbene enyne complexes is reported. In this study the steric and electronic effects have been evaluated. A diversion from the normal course of the reaction mechanism is observed.