250-35-1Relevant academic research and scientific papers
Synthesis and reactivity of dipropargylic disulfides: tandem rearrangements, cyclization, and oxidative dimerization
Braverman, Samuel,Cherkinsky, Marina,Meridor, David,Sprecher, Milon
scheme or table, p. 1925 - 1930 (2010/04/24)
Synthesis and facile rearrangement and cyclization reaction of new dipropargylic disulfides are described. A possible mechanism for these transformations involving an initial double [2,3]-sigmatropic rearrangement to the elusive diallenyl disulfides via a thiosulfoxide intermediates is suggested.
REDUCTION DES CONTRAINTES STERIQUES (EMPECHEMENT A LA CONJUGAISON) DANS LES POLY(DIALKYL-3,4-THIOPHENES)
Garreau, R.,Roncali, J.,Garnier, F.,Lemaire, M.
, p. 93 - 98 (2007/10/02)
Cyclopenta thiophene, cyclopenta thiophene and thieno thiophene have been synthesized.The electropolymerization of these monomers was attempt.The electrical properties of poly(cyclopenta thiophene) are intermediate between those of poly(3-methylthiophene) and poly(3,4-dimethyl thiophene).
Generation and Characterization of the Parent 2λ4?2-Thienothiophene
Nakayama, Juzo,Ishii, Akihiko,Kobayashi, Yasunobu,Hoshino, Masamatsu
, p. 959 - 960 (2007/10/02)
The parent 2λ4?2-thienothiophene was generated by Pummerer dehydration of 1H,3H-thienothiophene 2-oxide and characterized by chemical trapping experiments.
